Evidence map›Paper›PMID 37291130›Full record

ArticleNature communications2023

Revealing core-valence interactions in solution with femtosecond X-ray pump X-ray probe spectroscopy.

Robert B Weakly, Chelsea E Liekhus-Schmaltz, Benjamin I Poulter, Elisa Biasin, Roberto Alonso-Mori, Andrew Aquila, Sébastien Boutet, Franklin D Fuller, Phay J Ho, Thomas Kroll and 7 more

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.8field-weighted citation impact, top 30% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 4 citations in OpenAlex.

  1. Multiplet lines in seeded stimulated MnPhysical review applied · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

17 authors at 5 institutions in 1 country.

Robert B WeaklyDepartment of Chemistry, University of Washington, Seattle, WA, 98195, USA.ORCID http://orcid.org/0000-0001-9245-5720
Chelsea E Liekhus-SchmaltzDepartment of Chemistry, University of Washington, Seattle, WA, 98195, USA.
Benjamin I PoulterDepartment of Chemistry, University of Washington, Seattle, WA, 98195, USA.ORCID http://orcid.org/0000-0002-2007-0319
Elisa BiasinStanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.ORCID http://orcid.org/0000-0002-7276-4224
Roberto Alonso-MoriLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.ORCID http://orcid.org/0000-0002-5357-0934
Andrew AquilaLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.ORCID http://orcid.org/0000-0003-0358-2774
Sébastien BoutetLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.ORCID http://orcid.org/0000-0003-3928-1244
Franklin D FullerLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
Phay J HoChemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, IL, 60439, USA.ORCID http://orcid.org/0000-0001-5214-2180
Thomas KrollStanford Synchrotron Radiation Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
Caroline M LoeDepartment of Chemistry, University of Washington, Seattle, WA, 98195, USA.
Alberto LutmanLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.ORCID http://orcid.org/0000-0001-5791-9198
Diling ZhuLinac Coherent Light Source, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.
Uwe BergmannDepartment of Physics, University of Wisconsin-Madison, Madison, WI, 53706, USA.ORCID http://orcid.org/0000-0001-5639-166X
Robert W SchoenleinStanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, CA, 94025, USA.ORCID http://orcid.org/0000-0002-6066-7566
Niranjan GovindPhysical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, WA, 99352, USA.ORCID http://orcid.org/0000-0003-3625-366X
Munira KhalilDepartment of Chemistry, University of Washington, Seattle, WA, 98195, USA. mkhalil@uw.edu.ORCID http://orcid.org/0000-0002-6508-4124
SLAC National Accelerator Laboratory · USUniversity of Washington · USPacific Northwest National Laboratory · USArgonne National Laboratory · USUniversity of Wisconsin–Madison · US

Funding

National Science Foundation (NSF) DGE-1762114U.S. Department of Energy (DOE) DE-AC02-06CH11357U.S. Department of Energy (DOE) DE-AC02-76SF00515U.S. Department of Energy (DOE) DE-SC0019277U.S. Department of Energy (DOE) DE-SC0023249U.S. Department of Energy (DOE) KC-030105172685U.S. Department of Energy (DOE) KC-030105180818
6 · The paper itself

Abstract

Femtosecond pump-probe spectroscopy using ultrafast optical and infrared pulses has become an essential tool to discover and understand complex electronic and structural dynamics in solvated molecular, biological, and material systems. Here we report the experimental realization of an ultrafast two-color X-ray pump X-ray probe transient absorption experiment performed in solution. A 10 fs X-ray pump pulse creates a localized excitation by removing a 1s electron from an Fe atom in solvated ferro- and ferricyanide complexes. Following the ensuing Auger-Meitner cascade, the second X-ray pulse probes the Fe 1s → 3p transitions in resultant novel core-excited electronic states. Careful comparison of the experimental spectra with theory, extracts +2 eV shifts in transition energies per valence hole, providing insight into correlated interactions of valence 3d with 3p and deeper-lying electrons. Such information is essential for accurate modeling and predictive synthesis of transition metal complexes relevant for applications ranging from catalysis to information storage technology. This study demonstrates the experimental realization of the scientific opportunities possible with the continued development of multicolor multi-pulse X-ray spectroscopy to study electronic correlations in complex condensed phase systems.

Indexed as

Coordination ComplexesX-Ray Absorption SpectroscopyX-RaysCoordination Complexes

Identifiers

PMID37291130
PMCPMC10250333
OpenAlexW4379967243

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.