ArticleNature communications2023
Multi-chiral materials comprising metallosupramolecular and covalent helical polymers containing five axial motifs within a helix.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Recent advances in the stereoselective synthesis of distal biaxially chiral molecules.Beilstein journal of organic chemistry · 2026Review
- Zn-IMP 3D Coordination Polymers for Drug Delivery: Crystal Structure and Computational Studies.Polymers · 2025Article
- Consecutive Complex Aggregation Pathway in Covalent Helical Polymer-Metal Complexes: Nanospheres with Controlled P/M Macroscopic Chirality.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Fano Resonance-Associated Plasmonic Circular Dichroism in a Multiple-Dipole Interaction Born-Kuhn Model.Sensors (Basel, Switzerland) · 2024Article
- Wide-range tunable circularly polarized luminescence in triphenylamine supramolecular polymers via charge-transfer complexation.Nature communications · 2024Article
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Authors and funding
4 authors.
Funding
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Abstract
Supramolecular and covalent polymers share multiple structural effects such as communication mechanisms among monomer repeating units, which are related to their axial helical structure. Herein, a unique multi-helical material combining information from both metallosupramolecular and covalent helical polymers is presented. In this system, the helical structure described by the poly(acetylene) (PA) backbone (cis-cisoidal, cis-transoidal) guides the pendant groups in a fashion where a tilting degree emerges between a pendant and the adjacent ones. As a result, a multi-chiral material is formed comprising four or five axial motifs when the polyene skeleton adopts either a cis-transoidal or cis-cisoidal configuration: the two coaxial helices-internal and external-and the two or three chiral axial motifs described by the bispyridyldichlorido Pt
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Registered trials
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