ArticleThe journal of physical chemistry. B2023
Does the Sum-Frequency Generation Signal of Aromatic C-H Vibrations Reflect Molecular Orientation?
Article in The journal of physical chemistry. B, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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4 citing papers in PubMed.
- When Do Ionic Liquids Stop Behaving as Ionic Liquids? Assessing the Environmental Relevance of Ion Pairing.Molecules (Basel, Switzerland) · 2026Review
- Enhancing the detection of LTP through lyophilized protein samples and NIR spectroscopy with explainable deep learning.Scientific reports · 2026Article
- Orientational Behavior and Vibrational Response of Glycine at Aqueous Interfaces.The journal of physical chemistry letters · 2024Article
- Site-selective chemical reactions by on-water surface sequential assembly.Nature communications · 2023Article
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Authors and funding
7 authors.
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Abstract
Organic molecules with aromatic groups at the aqueous interfaces play a central role in atmospheric chemistry, green chemistry, and on-water synthesis. Insights into the organization of interfacial organic molecules can be obtained using surface-specific vibrational sum-frequency generation (SFG) spectroscopy. However, the origin of the aromatic C-H stretching mode peak is unknown, prohibiting us from connecting the SFG signal to the interfacial molecular structure. Here, we explore the origin of the aromatic C-H stretching response by heterodyne-detected SFG (HD-SFG) at the liquid/vapor interface of benzene derivatives and find that, irrespective of the molecular orientation, the sign of the aromatic C-H stretching signals is negative for all the studied solvents. Together with density functional theory (DFT) calculations, we reveal that the interfacial quadrupole contribution dominates, even for the symmetry-broken benzene derivatives, although the dipole contribution is non-negligible. We propose a simple evaluation of the molecular orientation based on the aromatic C-H peak area.
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