ArticleJournal of the American Chemical Society2023
Defining Unidirectional Motions and Structural Reconfiguration in a Macrocyclic Molecular Motor.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- A photochemical rotor bias in dual molecular motors.Nature chemistry · 2026Article
- A supercharged molecular motor operating by constitutional alteration and proton transfer.Nature chemistry · 2026Article
- Multistate photoswitches beyond on and off.Nature communications · 2026Review
- Synthesis of β,β-Dinaphthyl Amino Acids: Towards Molecular Gearing in Peptides and Mini-Proteins.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Multi-State Redox and Light-Driven Switching of Pseudorotaxanation and Cation Shuttling.Journal of the American Chemical Society · 2025Article
- Structural Influence of the Chemical Fueling System on a Catalysis-Driven Rotary Molecular Motor.Journal of the American Chemical Society · 2025Article
- Hemiphosphoindigos as a platform for chiroptical or water soluble photoswitching.Nature communications · 2025Article
- Coupling Rotary Motion to Helicene Inversion within a Molecular Motor.Angewandte Chemie (International ed. in English) · 2025Article
- Directionality Reversal and Shift of Rotational Axis in a Hemithioindigo Macrocyclic Molecular Motor.Journal of the American Chemical Society · 2024Article
- Controlled interconversion of macrocyclic atropisomers via defined intermediates.Nature communications · 2024Article
- Stepwise Operation of a Molecular Rotary Motor Driven by an Appel Reaction.Journal of the American Chemical Society · 2024Article
- A photochemical method to evidence directional molecular motions.Nature communications · 2023Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The construction of sophisticated molecular machines requires not only precise control of energy fueled motions but their integration into larger functional architectures. Macrocyclization of molecular motors is a way to harness the intrinsic directionality of their rotation and use them to actively power different processes at the nano-scale. An effective concept in this regard uses a defined fragment of the molecular motor as a revolving door within the macrocycle. In this way, motor motions can be transmitted to distant structural entities, other rotations can be actively accelerated, or mechanical molecular threading events can be realized. In this work, a dual macrocyclization approach is presented, which not only allows to supersize the revolving door element but also structurally reconfigure the macrocycle in which the revolving door rotates. Unique possibilities for a multi-level precision control over integrated directional motions are thus opened up without deteriorating the functionality of the molecular machine.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.