ArticleACS catalysis2020
Rhodium-Stabilized Diarylcarbenes Behaving as Donor/Acceptor Carbenes.
Article in ACS catalysis, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- eCyclopropanation - a safe and scalable electrochemical route to cyclopropanes.Chemical science · 2026Article
- Site- and enantioselective B-H functionalization of carboranes.Nature communications · 2025Article
- Heterogeneous Fe-N-C Catalyst for Aerobic Dehydrogenation of Hydrazones to Diazo Compounds Used for Carbene Transfer.Journal of the American Chemical Society · 2024Article
- Diaryldiazoketones as Effective Carbene Sources for Highly Selective Rh(II)-Catalyzed Intermolecular C-H Functionalization.Journal of the American Chemical Society · 2024Article
- Enantioselective Synthesis of Triarylmethanes via Intermolecular C-H Functionalization of Cyclohexadienes with Diaryldiazomethanes.Organic letters · 2023Article
- In-situ Kinetic Studies of Rh(II)-Catalyzed C-H Functionalization to Achieve High Catalyst Turnover Numbers.ACS catalysis · 2022Article
- Palladium-catalyzed intramolecular enantioselective C(spChemical science · 2022Article
- Organocatalytic discrimination of non-directing aryl and heteroaryl groups: enantioselective synthesis of bioactive indole-containing triarylmethanes.Chemical science · 2022Article
- Proton or Carbene Transfer? On the Dark and Light Reaction of Diazoalkanes with Alcohols.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Divergent stereochemical outcomes in the insertion of donor/donor carbenes into the C-H bonds of stereogenic centers.Chemical science · 2022Article
- Catalyst-Controlled Stereoselective Barton-Kellogg Olefination.Angewandte Chemie (International ed. in English) · 2021Article
- Photochemical Carbene Transfer Reactions of Aryl/Aryl Diazoalkanes-Experiment and Theory*.Angewandte Chemie (International ed. in English) · 2021Article
- Transition Metal Catalyzed Insertion Reactions with Donor/Donor Carbenes.Angewandte Chemie (International ed. in English) · 2021Review
- Enantioselective Diarylcarbene Insertion into Si-H Bonds Induced by Electronic Properties of the Carbenes.Journal of the American Chemical Society · 2020Article
- Enantioselective Si-H Insertion Reactions of Diarylcarbenes for the Synthesis of Silicon-Stereogenic Silanes.Journal of the American Chemical Society · 2020Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Rhodium-stabilized diaryl carbenes typically generated from diaryldiazomethanes have been generally classified as donor/donor carbenes. This combined computational and experimental study demonstrates that diarylcarbenes display reactivity characteristics that are more reminiscent of donor/acceptor carbenes. When the reactions are carried out with chiral dirhodium catalysts, Rh
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Registered trials
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