ArticleNature communications2023
On the role of history-dependent adsorbate distribution and metastable states in switchable mesoporous metal-organic frameworks.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
5 citing papers in PubMed.
- Programmable Guest-Induced 5-Phase-Transition Topological Reconstructions of Cobalt Formate Metal-Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Harnessing cooperative sorbate-sorbent adaptation in a flexible metal-organic framework for switchable hydrocarbon separation.Science advances · 2026Article
- Negative gas adsorption transitions and pressure amplification phenomena in porous frameworks.Chemical Society reviews · 2025Review
- Supramolecular systems and their connection with metal-organic structures.Frontiers in chemistry · 2024Review
- Nanoporous Frameworks with High Porosity and Unexpected Rigid Framework Topologies Based on Odd-Numbered Ring-Expanded Linkers.Small science · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
A unique feature of metal-organic frameworks (MOFs) in contrast to rigid nanoporous materials is their structural switchabilty offering a wide range of functionality for sustainable energy storage, separation and sensing applications. This has initiated a series of experimental and theoretical studies predominantly aiming at understanding the thermodynamic conditions to transform and release gas, but the nature of sorption-induced switching transitions remains poorly understood. Here we report experimental evidence for fluid metastability and history-dependent states during sorption triggering the structural change of the framework and leading to the counterintuitive phenomenon of negative gas adsorption (NGA) in flexible MOFs. Preparation of two isoreticular MOFs differing by structural flexibility and performing direct in situ diffusion studies aided by in situ X-ray diffraction, scanning electron microscopy and computational modelling, allowed assessment of n-butane molecular dynamics, phase state, and the framework response to obtain a microscopic picture for each step of the sorption process.
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Registered trials
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