Evidence map›Paper›PMID 37267593›Full record

ArticleJournal of the American Chemical Society2023

Main Group Molecular Switches with Swivel Bifurcated to Trifurcated Hydrogen Bond Mode of Action.

Gavin Hum, Si Jia Isabel Phang, How Chee Ong, Felix León, Shina Quek, Yi Xin Joycelyn Khoo, Chenfei Li, Yongxin Li, Jack K Clegg, Jesús Díaz and 2 more

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Probing the Hidden Photoisomerization of a Symmetric Phosphaalkene Switch.Angewandte Chemie (International ed. in English) · 2025
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Gavin HumSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Si Jia Isabel PhangSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
How Chee OngSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Felix LeónSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Shina QuekSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Yi Xin Joycelyn KhooSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Chenfei LiSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Yongxin LiSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.
Jack K CleggSchool of Chemistry and Molecular Biosciences, The University of Queensland, Cooper Road, St Lucia 4072, Queensland, Australia.ORCID 0000-0002-7140-5596
Jesús DíazDepartamento de Química Orgánica e Inorgánica, Facultad de Veterinaria Extremadura, Avda de la Universidad s/n, Cáceres 10003, Spain.ORCID 0000-0001-9955-7818
Mihaiela C StuparuSchool of Chemistry, Chemical Engineering & Biotechnology, Nanyang Technological University, 21 Nanyang Link, 637371 Singapore, Singapore.ORCID 0000-0001-8663-6189
Felipe GarcíaDepartamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, Julián Claveria 8, Oviedo 33006, Asturias, Spain.ORCID 0000-0002-9605-3611

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Artificial molecular machines have captured the full attention of the scientific community since Jean-Pierre Sauvage, Fraser Stoddart, and Ben Feringa were awarded the 2016 Nobel Prize in Chemistry. The past and current developments in molecular machinery (rotaxanes, rotors, and switches) primarily rely on organic-based compounds as molecular building blocks for their assembly and future development. In contrast, the main group chemical space has not been traditionally part of the molecular machine domain. The oxidation states and valency ranges within the p-block provide a tremendous wealth of structures with various chemical properties. Such chemical diversity─when implemented in molecular machines─could become a transformative force in the field. Within this context, we have rationally designed a series of NH-bridged acyclic dimeric cyclodiphosphazane species, [(μ-NH){PE(μ-N

Identifiers

PMID37267593
PMCPMC10273318

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.