ReviewChemical science2023
Shining light on halogen-bonding complexes: a catalyst-free activation mode of carbon-halogen bonds for the generation of carbon-centered radicals.
Review in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
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The trial behind it
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Who cites it
15 citing papers in PubMed.
- Deprotection of benzyl ethersGreen chemistry : an international journal and green chemistry resource : GC · 2026Article
- Photochemistry of Halogen-Bonded Complexes: Light-Initiated Electron Transfer from Halide Anions to Bromo-Substituted Electrophiles.ACS omega · 2026Article
- Multicomponent Photochemical Assembly of C(spACS organic & inorganic Au · 2026Article
- Dual Semiconductor-Photoredox/Halogen-Bonding Organocatalyzed Cascade Sulfonylation/Cyclization of Alkynes and Alkenes with RSOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Decontamination from water pollutants and pathogens by electrospun nanofibers doped with heavy-atom-free borafluorene-BODIPY photosensitizers.Beilstein journal of nanotechnology · 2026Article
- Probing the Stability of Halogenated Carbon Atomic Wires in Electrospun Nanofibers via Raman Spectroscopy.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations.Chemical reviews · 2025Review
- Defluorinative Cyclization of Enamides with Fluoroalkyl Halides Through Two Vicinal C(spAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- A Dual Catalytic Approach for the Halogen-Bonding-Mediated Reductive Cleavage of α-Bromodifluoroesters and Amides.The Journal of organic chemistry · 2025Article
- Photogeneration of α-Bimetalloid Radicals via Selective Activation of Multifunctional C1 Units.Journal of the American Chemical Society · 2024Article
- Advancements in visible-light-induced reactions via alkenyl radical intermediates.Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology · 2024Review
- Iodoarene-directed photoredox β-C(spChemical science · 2024Article
- Transition-metal-catalyst-free electroreductive alkene hydroarylation with aryl halides under visible-light irradiation.Beilstein journal of organic chemistry · 2024Article
- Photochemical halogen-bonding assisted carbothiophosphorylation reactions of alkenyl and 1,3-dienyl bromides.Chemical science · 2023Article
- Difluoroalkylation of Anilines via Photoinduced Methods.The Journal of organic chemistry · 2023Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The discovery of new activation modes for the creation of carbon-centered radicals is a task of great interest in organic chemistry. Classical activation modes for the generation of highly reactive radical carbon-centered intermediates typically relied on thermal activation of radical initiators or irradiation with unsafe energetic UV light of adequate reaction precursors. In recent years, photoredox chemistry has emerged as a leading strategy towards the catalytic generation of C-centered radicals, which enabled their participation in novel synthetic organic transformations which is otherwise very challenging or even impossible to take place. As an alternative to these activation modes for the generation of C-centered radicals, the pursuit of greener, visible-light initiated reactions that do not necessitate a photoredox/metal catalyst has recently caught the attention of chemists. In this review, we covered recent transformations, which rely on photoactivation with low-energy light of a class of EDA complexes, known as halogen-bonding adducts, for the creation of C-centered radicals.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.