ArticleChemical science2023
Magnetic hysteresis and large coercivity in bisbenzimidazole radical-bridged dilanthanide complexes.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
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Who cites it
20 citing papers in PubMed.
- Magneto-Optical Spectroscopy Across Three Oxidation States of a Europium Terpyridine Complex.Inorganic chemistry · 2026Article
- A High Energy Barrier DyChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Magnetic Blocking in Fluoflavine Radical-Bridged Dilanthanide Complexes.Journal of the American Chemical Society · 2025Article
- Triply halogen-bridged erbium compounds with hard single-molecule magnet behavior.Communications chemistry · 2025Article
- Synthesis and Electronic Structure of a Tetraazanaphthalene Radical-Bridged Yttrium Complex.ACS organic & inorganic Au · 2025Article
- A tetraazanaphthalene radical-bridged dysprosium single-molecule magnet with a large coercive field.Chemical science · 2025Article
- Reduction of Rare-Earth Stannole Sandwich Complexes to Tin-Based Radical Ligands and Tin-Tin Bonds.Angewandte Chemie (International ed. in English) · 2025Article
- Magnetic hysteresis in 1D organometallic lanthanide chain compounds containing 4,4'-bipyridine.Chemical science · 2025Article
- Exchange Bias in a Dinuclear Erbium Single-Molecule Magnet Bridged by a Helicene Ligand.Inorganic chemistry · 2025Article
- Reduction of Hexaazatrinaphthylenes by Masked Divalent Lanthanide Dinitrogen Reagents.Inorganic chemistry · 2025Article
- Slow Magnetic Relaxation in a Rare, Neutral, Formally Divalent Terbium Bis(amide) Complex.Inorganic chemistry · 2025Article
- A Linear Dysprosium(II) Metallocene with a High Effective Energy Barrier and Magnetic Hysteresis up to 70 Kelvin.Journal of the American Chemical Society · 2025Article
- Single-molecule Magnet Properties of Silole- and Stannole-ligated Erbium Cyclo-octatetraenyl Sandwich Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Magnetic Hysteresis in a Dysprosium Bis(amide) Complex.Journal of the American Chemical Society · 2025Article
- Isolation of Elusive Fluoflavine Radicals in Two Differing Oxidation States.Journal of the American Chemical Society · 2024Article
- Construction of intermolecular σ-hole interactions in rare earth metallocene complexes using a 2,3,4,5-tetraiodopyrrolyl anion.Chemical science · 2024Article
- Linear, Electron-Rich Erbium Single-Molecule Magnet with Dibenzocyclooctatetraene Ligands.Inorganic chemistry · 2024Article
- Guanidinate Yttrium Complexes Containing Bipyridyl and Bis(benzimidazolyl) Radicals.Inorganic chemistry · 2024Article
- Article
- Dipolar Coupling as a Mechanism for Fine Control of Magnetic States in ErCOT-Alkyl Molecular Magnets.Journal of the American Chemical Society · 2024Article
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A judicious combination of radical ligands innate to diffuse spin orbitals with paramagnetic metal ions elicits strong magnetic exchange coupling which leads to properties important for future technologies. This metal-radical approach aids in effective magnetic communication of especially lanthanide ions as their 4f orbitals are contracted and not readily accessible. Notably, a high spin density on the donor atoms of the radical is required for strong coupling. Such molecules are extremely rare owing to high reactivity rendering their isolation challenging. Herein, we present two unprecedented series of bisbenzimidazole-based dilanthanide complexes [(Cp*
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