ArticleNature chemistry2023
Multistep, site-selective noncovalent synthesis of two-dimensional block supramolecular polymers.
Article in Nature chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Supramolecular morphological transition driven by nonequilibrium break-and-build self-organisation.Nature communications · 2026Article
- Additive-induced kinetic control and chiral amplification in circularly polarized luminescence (CPL)-emitting secondary supramolecular polymers.Chemical science · 2026Article
- Controlled assembly of two-dimensional porphyrin heterostructures toward directed energy transfer and charge separation.Nature communications · 2026Article
- Light-regulated templated self-assembly of bilayered nanotoroids.Chemical science · 2026Article
- Linear and branched supramolecular polymers formed from isomeric monomers as revealed by solution viscoelasticity.Chemical science · 2026Article
- Noncovalent synthesis of higher-order super-heterostructures from structurally distinct molecular π-systems via secondary nucleation.Nature communications · 2026Article
- One- and Two-Dimensional Polymorphism in a Hydrogen-Bonding Bis-Ureido-Squaramide.Angewandte Chemie (International ed. in English) · 2026Article
- "Optochemistry", when chemistry meets optics.Science and technology of advanced materials · 2026Review
- Kinetically controlled self-assembly of Zn-porphyrin nanostructuresRSC advances · 2025Article
- Crystallization-driven two-dimensional assemblies from a phenothiazine-conjugated poly(l-lactide): redox-responsive tunable emission, white-light harvesting and surface-enabled nanoparticle decoration.Chemical science · 2025Article
- Crafting defects in two-dimensional organic platelets via seeded coassembly enables emergent molecular recognition.Nature communications · 2025Article
- Noncovalent Synthesis of Topological Heterostructures Using a Site-Selective Electrostatic Co-Assembly Strategy.Angewandte Chemie (International ed. in English) · 2025Article
- Inversion of supramolecular chirality by photo-enhanced secondary nucleation.Nature nanotechnology · 2025Article
- Secondary nucleation as a strategy towards hierarchically organized mesoscale topologies in supramolecular polymerization.Nature chemistry · 2025Review
- Chirality Evolution of Supramolecular Helices by Electron Transfer Assisted Secondary Nucleation.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- A coopetition-driven strategy of parallel/perpendicular aromatic stacking enabling metastable supramolecular polymerization.Nature communications · 2024Article
- Modulating self-assembly and polymorph transitions in bisdendronized squaramides.Communications chemistry · 2024Article
- Pathway control in metallosupramolecular polymerization of a monoalkynylplatinum(ii) terpyridine complex through competitive complex formation.Chemical science · 2024Article
- Concentric hollow multi-hexagonal platelets from a small molecule.Nature communications · 2024Article
- Noncovalent synthesis of homo and hetero-architectures of supramolecular polymers via secondary nucleation.Nature communications · 2024Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Although the principles of noncovalent bonding are well understood and form the basis for the syntheses of many intricate supramolecular structures, supramolecular noncovalent synthesis cannot yet achieve the levels of precision and complexity that are attainable in organic and/or macromolecular covalent synthesis. Here we show the stepwise synthesis of block supramolecular polymers from metal-porphyrin derivatives (in which the metal centre is Zn, Cu or Ni) functionalized with fluorinated alkyl chains. These monomers first undergo a one-dimensional supramolecular polymerization and cyclization process to form a toroidal structure. Subsequently, successive secondary nucleation, elongation and cyclization steps result in two-dimensional assemblies with concentric toroidal morphologies. The site selectivity endowed by the fluorinated chains, reminiscent of regioselectivity in covalent synthesis, enables the precise control of the compositions and sequences of the supramolecular structures, as demonstrated by the synthesis of several triblock supramolecular terpolymers.
Identifiers
37264101What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.