ArticleNature communications2023
Polycage membranes for precise molecular separation and catalysis.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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Who cites it
21 citing papers in PubMed.
- Ion-Permselective Porous Organic Cage Membranes.Angewandte Chemie (International ed. in English) · 2026Review
- Click-polymerized polyenamine membranes for efficient lithium extraction.Nature communications · 2026Article
- From triangles to squares - chiral, overcrowded polyimine macrocycles of significant chiroptical response enable the capture of chlorinated solvents.Scientific reports · 2026Article
- Macrocycle-assembled membranes for high-salinity organic wastewater treatment.Nature communications · 2026Article
- Polyamide nanofilms with Janus microporous framework for sustainable solvent filtration.Nature communications · 2025Article
- Microstructure engineering of polyamide membranes for ultrafast polar and non-polar solvent transport.Nature communications · 2025Article
- Solvent Transport in Disordered and Dynamic Membrane Pores: Implications for Reverse Osmosis and Nanofiltration Membranes.Environmental science & technology · 2025Article
- Porous Organic Cages as Building Blocks for Framework Materials.Angewandte Chemie (International ed. in English) · 2025Review
- Advanced Materials-Based Nanofiltration Membranes for Efficient Removal of Organic Micropollutants in Water and Wastewater Treatment.Membranes · 2025Review
- Molecular manipulation of polyamide nanostructures reconciles the permeance-selectivity threshold for precise ion separation.Nature communications · 2025Article
- Ionic organic cage as a versatile platform for immobilizing chemical and enzymatic sites for chemoenzymatic catalysis.Nature communications · 2025Article
- Template-directed self-assembly of porphyrin nanorings through an imine condensation reaction.Chemical science · 2025Article
- Hydrodynamic Fluidic Pump Empowered Sensitive Recognition and Active Transport of Hydrogen Peroxide in 1D Channels.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Engineering a Surfactant Trap via Postassembly Modification of an Imine Cage.Chemistry of materials : a publication of the American Chemical Society · 2024Article
- Ultraselective Macrocycle Membranes for Pharmaceutical Ingredients Separation in Organic Solvents.Nature communications · 2024Article
- Dual-phase microporous polymer nanofilms by interfacial polymerization for ultrafast molecular separation.Science advances · 2024Article
- Highlights from the 57th Bürgenstock Conference on Stereochemistry 2024.Chemical science · 2024Article
- Precision ion separation via self-assembled channels.Nature communications · 2024Article
- Sub-8 nm networked cage nanofilm with tunable nanofluidic channels for adaptive sieving.Nature communications · 2024Article
- Smart touchless human-machine interaction based on crystalline porous cages.Nature communications · 2024Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The evolution of the chemical and pharmaceutical industry requires effective and less energy-intensive separation technologies. Engineering smart materials at a large scale with tunable properties for molecular separation is a challenging step to materialize this goal. Herein, we report thin film composite membranes prepared by the interfacial polymerization of porous organic cages (POCs) (RCC3 and tren cages). Ultrathin crosslinked polycage selective layers (thickness as low as 9.5 nm) are obtained with high permeance and strict molecular sieving for nanofiltration. A dual function is achieved by combining molecular separation and catalysis. This is demonstrated by impregnating the cages with highly catalytically active Pd nanoclusters ( ~ 0.7 nm). While the membrane promotes a precise molecular separation, its catalytic activity enables surface self-cleaning, by reacting with any potentially adsorbed dye and recovering the original performance. This strategy opens opportunities for the development of other smart membranes combining different functions and well-tailored abilities.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.