ArticleNature communications2023
Unraveling chirality transfer mechanism by structural isomer-derived hydrogen bonding interaction in 2D chiral perovskite.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed.
- Coupled Molecular and Framework Descriptors for Band-Edge Spin Splitting in Chiral Hybrid Organic-Inorganic Perovskites.Journal of the American Chemical Society · 2026Article
- Chiral Metal Halides toward Circularly Polarized Photodetectors.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Contactless Detection of Giant Helicity-Dependent Photovoltage in Chiral 2D Perovskites.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Narrow-Bandgap Zero-Dimensional Chiral Hybrid Perovskites.Journal of the American Chemical Society · 2026Article
- Dimensional engineering in chiral layered hybrid perovskites for high-anisotropy self-powered circularly polarized light detection.Chemical science · 2026Article
- Chiral manganese halide isomers: decoding the spatial stacking effect on second-harmonic generation circular dichroism.Chemical science · 2026Article
- Chiral Metal Halide Perovskites for Spin-Polarized Light-Emitting Diodes.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Polarized luminescence in halide perovskite nanocrystals: from fundamental microscopic mechanisms to advanced optoelectronic applications.Frontiers in chemistry · 2026Review
- Organic A-cations in metal halide perovskite photovoltaics.Nature reviews. Chemistry · 2026Review
- Ligand-Driven Chirality in Perovskites for Advanced Optoelectronics.ACS applied materials & interfaces · 2025Review
- Multifunctional Chiral Halide Perovskites: Advancing Chiro-Optics, Chiro-Optoelectronics, and Spintronics.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Chiral Phonons in 2D Halide Perovskites.Nano letters · 2025Article
- Chiral Perovskite Single Crystals: Toward Promising Design and Application.Materials (Basel, Switzerland) · 2025Review
- Article
- Manipulating perovskite structural asymmetry for high-performing self-powered full-stokes polarimetry.Science advances · 2025Article
- Remote chirality transfer in low-dimensional hybrid metal halide semiconductors.Nature chemistry · 2025Article
- Remote control of chirality in hybrid perovskite materials.Nature chemistry · 2025Article
- Intense Circular Dichroism and Spin Selectivity in AgBiSAdvanced materials (Deerfield Beach, Fla.) · 2024Article
- A chemical perspective on the chiral induced spin selectivity effect.National science review · 2024Review
- Giant chiral amplification of chiral 2D perovskites via dynamic crystal reconstruction.Science advances · 2024Article
Corrections and comments
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Authors and funding
12 authors.
Funding
Abstract
In principle, the induced chirality of hybrid perovskites results from symmetry-breaking within inorganic frameworks. However, the detailed mechanism behind the chirality transfer remains unknown due to the lack of systematic studies. Here, using the structural isomer with different functional group location, we deduce the effect of hydrogen-bonding interaction between two building blocks on the degree of chirality transfer in inorganic frameworks. The effect of asymmetric hydrogen-bonding interaction on chirality transfer was clearly demonstrated by thorough experimental analysis. Systematic studies of crystallography parameters confirm that the different asymmetric hydrogen-bonding interactions derived from different functional group location play a key role in chirality transfer phenomena and the resulting spin-related properties of chiral perovskites. The methodology to control the asymmetry of hydrogen-bonding interaction through the small structural difference of structure isomer cation can provide rational design paradigm for unprecedented spin-related properties of chiral perovskite.
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