ReviewACS physical chemistry Au2023
On the Temperature Sensitivity of Electrochemical Reaction Thermodynamics.
Review in ACS physical chemistry Au, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
9 citing papers in PubMed.
- The Interplay between Interfacial Solvation and Surface Kinetics Tunes the Selectivity between Hydrogen Evolution and Zinc Electrodeposition.Journal of the American Chemical Society · 2026Article
- Effects of Supporting Electrolyte and Solvent on the Thermodynamics and Kinetics of Reduction Reactions in a Keggin-Type Polyoxotungstate.Inorganic chemistry · 2026Article
- Interfacial solvation pre-organizes the transition state of the oxygen evolution reaction.Nature chemistry · 2026Article
- Enhancing Temperature Sensitivity of Redox Potential via Redox-Induced Change in Copper Coordination Number by an External Ligand.Journal of the American Chemical Society · 2026Article
- Quantification of redox thermodynamics shifts within coacervates.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Temperature-dependent microfluidic impedance spectroscopy for non-invasive biofluid characterization.Biomicrofluidics · 2025Article
- Best Practices for Variable-Temperature Electrochemistry Experiments and Data Reporting.ACS energy letters · 2025Article
- High-throughput parallel testing of ten photoelectrochemical cells for water splitting: case study on the effects of temperature in hematite photoanodes.Sustainable energy & fuels · 2024Article
- A capacitive laser-induced graphene based aptasensor for SARS-CoV-2 detection in human saliva.PloS one · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Herein, we report a method to estimate the thermodynamic potentials of electrochemical reactions at different temperatures. We use a two-term Taylor series approximation of thermodynamic potential as a function of temperature, and we calculate the temperature sensitivity for a family of twenty seven known half reactions. We further analyze pairs of cathode and anode half-cells to pinpoint optimal voltage matches and discuss implications of changes in temperature on overall cell voltages. Using these observations, we look forward to increased interest in temperature and idealized half-reaction pairing as experimental choices for the optimization of electrochemical processes.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.