ReviewMolecules (Basel, Switzerland)2023
The Reducing Agents in Sonochemical Reactions without Any Additives.
Review in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed, 24 citations in OpenAlex.
- Hydrodynamic cavitation for prebiotic ribose formation from HNational science review · 2026Article
- Optimization of protein extraction from skin tape strips for biomarker assessment.Scientific reports · 2026Article
- Improvement of colour and oxidative stability of red deer and beef meat under sonication treatment.Scientific reports · 2025Article
- Evaluation of HUltrasonics sonochemistry · 2024Article
- Soft Matter Electrolytes: Mechanism of Ionic Conduction Compared to Liquid or Solid Electrolytes.Materials (Basel, Switzerland) · 2024Review
- Sonochemical decomposition effects of nickelocene aiming for low-temperature and dispersant-free synthesis of nickel fine particle.Ultrasonics sonochemistry · 2024Article
- Solution-Phase Synthesis of KCl Nanocrystals Templated by PEO-PPO-PEO Triblock Copolymers Micelles.Polymers · 2024Article
Corrections and comments
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Authors and funding
1 author at 1 institution in 1 country.
Funding
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Abstract
It has been experimentally reported that not only oxidation reactions but also reduction reactions occur in aqueous solutions under ultrasound without any additives. According to the numerical simulations of chemical reactions inside an air or argon bubble in water without any additives under ultrasound, reducing agents produced from the bubbles are H, H2, HO2 (which becomes superoxide anion (O2-) in liquid water), NO, and HNO2 (which becomes NO2- in liquid water). In addition, H2O2 sometimes works as a reducing agent. As the reduction potentials of H and H2 (in strongly alkaline solutions for H2) are higher than those of RCHOH radicals, which are usually used to reduce metal ions, H and H2 generated from cavitation bubbles are expected to reduce metal ions to produce metal nanoparticles (in strongly alkaline solutions for H2 to work). It is possible that the superoxide anion (O2-) also plays some role in the sonochemical reduction of some solutes. In strongly alkaline solutions, hydrated electrons (e-aq) formed from H atoms in liquid water may play an important role in the sonochemical reduction of solutes because the reduction potential is extremely high. The influence of ultrasonic frequency on the amount of H atoms produced from a cavitation bubble is also discussed.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.