ArticleJACS Au2023
Observation of the Magnetic Ground State of the Two Smallest Triangular Nanographenes.
Article in JACS Au, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
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Who cites it
28 citing papers in PubMed, 81 citations in OpenAlex.
- Spin characteristics of organic radicals from a single-molecule junction perspective.Chemical science · 2026Review
- Spin and Charge Control of Topological End States in Chiral Graphene Nanoribbons on a 2D Ferromagnet.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- π-Radical Cascades to Peri-Fused Triangulene Dimers.Angewandte Chemie (International ed. in English) · 2026Article
- Benzo[cd]azulenyl: A Structural Isomer of Phenalenyl-Synthesis and Properties of Its Tri-tert-butyl-substituted Derivative and Formation of a Thermal- and Photoresponsive σ-Dimer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Metal-Free Ferromagnetism in Triangulene Two-Dimensional Frameworks.Journal of the American Chemical Society · 2026Article
- Spin State in Au Porphyrins Modulated by Charge Transfer on Au(111).Journal of the American Chemical Society · 2026Article
- On-surface synthesis and interfacial charge redistribution of open-shell [3]triangulene-fused porphyrins on Au(111).National science review · 2026Article
- DesignerNational science review · 2026Review
- Controlled magnetic bistability of a helical non-Kekulé hydrocarbon on a Au(111) surface.Nature communications · 2026Article
- Multiconfigurational Ground State of a Diradicaloid Characterized at the Atomic Scale.Journal of the American Chemical Society · 2025Article
- Synthesis and Characterization of a π-Extended Clar's Goblet.Journal of the American Chemical Society · 2025Article
- Zigzag graphene nanoribbons with periodic porphyrin edge extensions.Nature chemistry · 2025Article
- Spin States of Trioxotriangulene Controlled by Si-O Bond Formation and Dissociation on AuSiNano letters · 2025Article
- Systematic modulation of charge and spin in graphene nanoribbons on MgO.Nature communications · 2025Article
- On-Surface Synthesis of a Ferromagnetic Molecular Spin Trimer.Journal of the American Chemical Society · 2025Article
- Relating Radical Delocalization, Charge Transfer, and Magnetic Ground State in Acene-Derived Oxyradicals.Nano letters · 2025Article
- Reactivity and Magnetic Coupling of Triangulene Dimers Linked via para-Biphenyl Units.Angewandte Chemie (International ed. in English) · 2025Article
- A Route toward the On-Surface Synthesis of Organic Ferromagnetic Quantum Spin Chains.Journal of the American Chemical Society · 2025Article
- Article
- Distance and Voltage Dependence of Orbital Density Imaging Using a CO-Functionalized Tip in Scanning Tunneling Microscopy.ACS nano · 2025Article
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Fusion of three benzene rings in a triangular fashion gives rise to the smallest open-shell graphene fragment, the phenalenyl radical, whose π-extension leads to an entire family of non-Kekulé triangular nanographenes with high-spin ground states. Here, we report the first synthesis of unsubstituted phenalenyl on a Au(111) surface, which is achieved by combining in-solution synthesis of the hydro-precursor and on-surface activation by atomic manipulation, using the tip of a scanning tunneling microscope. Single-molecule structural and electronic characterizations confirm its open-shell
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.