ArticleJournal of the American Chemical Society2023
Direct Determination of the Rate of Intersystem Crossing in a Near-IR Luminescent Cr(III) Triazolyl Complex.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
What it found
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Who cites it
10 citing papers in PubMed.
- Interplay between ligand field strength and the nephelauxetic effect in chromium(iii) complexes with anionic amido ligands.Chemical science · 2026Article
- Homomolecular Photon Upconversion in a Perylene-Decorated Iron(III) Complex.Journal of the American Chemical Society · 2025Article
- Unraveling the photoredox chemistry of a molecular ruby.Chemical science · 2025Article
- Structural Control of Metal-Centered Excited States in Cobalt(III) Complexes via Bite Angle and π-π Interactions.Journal of the American Chemical Society · 2025Article
- Pushing the Thermodynamic and Kinetic Limits of Near-Infrared Emissive CrJournal of the American Chemical Society · 2025Article
- Molecular Design Principles for Photoactive Transition Metal Complexes: A Guide for "Photo-Motivated" Chemists.Journal of the American Chemical Society · 2025Review
- Dinuclear Cyclometalated Pincer Nickel(II) Complexes with Metal-Metal-to-Ligand Charge Transfer Excited States and Near-Infrared Emission.Angewandte Chemie (International ed. in English) · 2025Article
- Study of the Photophysical Properties and the DNA Binding of Enantiopure [Cr(TMP)Inorganic chemistry · 2024Article
- A Near-Infrared Luminescent Cr(III)Inorganic chemistry · 2024Article
- Oxidative two-state photoreactivity of a manganese(IV) complex using near-infrared light.Nature chemistry · 2024Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
A detailed understanding of the dynamics of photoinduced processes occurring in the electronic excited state is essential in informing the rational design of photoactive transition-metal complexes. Here, the rate of intersystem crossing in a Cr(III)-centered spin-flip emitter is directly determined through the use of ultrafast broadband fluorescence upconversion spectroscopy (FLUPS). In this contribution, we combine 1,2,3-triazole-based ligands with a Cr(III) center and report the solution-stable complex [Cr(btmp)
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Registered trials
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