ArticleJournal of thermal analysis and calorimetry2023
Thermal runaway evaluation on batch polyvinyl acetate emulsion polymerization from calorimetric measurement.
Article in Journal of thermal analysis and calorimetry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
1 citing paper in PubMed, 3 citations in OpenAlex.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Emulsion polymerization is the most applied method in the vinyl acetate monomer (VAM)-polyvinyl acetate (PVAc) process. However, the flammable property and unexpected bulk polymerization for the reactant and product may occur in the batch reactor or storage tank. VAM is reactive enough to decompose readily into free radicals and then, initiate the polymerization, which may contribute to heat accumulation due to the monomer, initiator, and solvent mixtures. This study attempts to analyze the exothermic reaction and compare the thermal runaway potential for various VAM solutions during PVAc polymerizations. Summarily, 50%, 70%, and 100% of VAM solutions reacting with 2,2'-azobis(2-methylpropionitrile) readily increase the self-heating rate with their concentration from adiabatic calorimetric tests. Furthermore, kinetic parameters of 50, 70, and 100 mass% VAM solutions were evaluated to elucidate the self-heating model associated with thermal analysis and to determine heat production mechanisms that are practical to proactive safety protocol for the PVAc emulsion process.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.