Evidence map›Paper›PMID 37221139›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2023

Non-Linear Kinetics of The Lithium Metal Anode on Li

Dheeraj Kumar Singh, Till Fuchs, Christian Krempaszky, Boris Mogwitz, Jürgen Janek

Open access · goldAbstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
2.0field-weighted citation impact, top 14% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed, 15 citations in OpenAlex.

  1. Article
  2. Article
  3. Article
  4. Non-Linear Kinetics of The Lithium Metal Anode on LiAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors at 2 institutions in 1 country.

Dheeraj Kumar SinghInstitute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, D-35392, Giessen, Germany.
Till FuchsInstitute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, D-35392, Giessen, Germany.
Christian KrempaszkyInstitute of Materials Science and Mechanics of Materials, Technical University of Munich, Boltzmannstrasse 15, D-85748, Garching, Germany.
Boris MogwitzInstitute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, D-35392, Giessen, Germany.
Jürgen JanekInstitute of Physical Chemistry, Justus-Liebig-University Giessen, Heinrich-Buff-Ring 17, D-35392, Giessen, Germany.ORCID https://orcid.org/0000-0002-9221-4756
Justus-Liebig-Universität Gießen · DETechnical University of Munich · DE

Funding

Department of EnergyGerman Federal Ministry of Education and ResearchGerman Federal Ministry of Education and Research 03XP0177AGerman Federal Ministry of Education and Research 03XP0224EGerman Federal Ministry of Education and Research 03XP0509B
6 · The paper itself

Abstract

Interfacial instability, viz., pore formation in the lithium metal anode (LMA) during discharge leading to high impedance, current focusing induced solid-electrolyte (SE) fracture during charging, and formation/behaviour of the solid-electrolyte interphase (SEI), at the anode, is one of the major hurdles in the development of solid-state batteries (SSBs). Also, understanding cell polarization behaviour at high current density is critical to achieving the goal of fast-charging battery and electric vehicle. Herein, via in situ electrochemical scanning electron microscopy (SEM) measurements, performed with freshly deposited lithium microelectrodes on transgranularly fractured fresh Li6PS5Cl (LPSCl), the LiǀLPSCl interface kinetics are investigated beyond the linear regime. Even at relatively small overvoltages of a few mV, the LiǀLPSCl interface shows non-linear kinetics. The interface kinetics possibly involve multiple rate-limiting processes, i.e., ion transport across the SEI and SE|SEI interfaces, as well as charge transfer across the LiǀSEI interface. The total polarization resistance R

Indexed as

dendrite growthlithium metal anodesmicrostructure assisted creepnon-linear kineticssolid-electrolyte interphase

Identifiers

PMID37221139
PMCPMC10401129
OpenAlexW4377861978

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.