Evidence map›Paper›PMID 37208325›Full record

ArticleNature communications2023

Insulator-to-metal-like transition in thin films of a biological metal-organic framework.

Pooja Sindhu, K S Ananthram, Anil Jain, Kartick Tarafder, Nirmalya Ballav

Abstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Pooja SindhuDepartment of Chemistry, Indian Institute of Science Education and Research, Dr. Homi Bhabha Road, Pune, 411 008, India.
K S AnanthramDepartment of Physics, National Institute of Technology Karnataka, Surathkal, Mangalore, 575 025, India.
Anil JainSolid State Physics Division, Bhabha Atomic Research Centre, Mumbai, 400085, India.ORCID http://orcid.org/0000-0002-5201-5947
Kartick TarafderDepartment of Physics, National Institute of Technology Karnataka, Surathkal, Mangalore, 575 025, India.ORCID http://orcid.org/0000-0002-6299-654X
Nirmalya BallavDepartment of Chemistry, Indian Institute of Science Education and Research, Dr. Homi Bhabha Road, Pune, 411 008, India. nballav@iiserpune.ac.in.ORCID http://orcid.org/0000-0002-7916-7334

Funding

DST | Science and Engineering Research Board (SERB) CRG/2020/001804
6 · The paper itself

Abstract

Temperature-induced insulator-to-metal transitions (IMTs) where the electrical resistivity can be altered by over tens of orders of magnitude are most often accompanied by structural phase transition in the system. Here, we demonstrate an insulator-to-metal-like transition (IMLT) at 333 K in thin films of a biological metal-organic framework (bio-MOF) which was generated upon an extended coordination of the cystine (dimer of amino acid cysteine) ligand with cupric ion (spin-1/2 system) - without appreciable change in the structure. Bio-MOFs are crystalline porous solids and a subclass of conventional MOFs where physiological functionalities of bio-molecular ligands along with the structural diversity can primarily be utilized for various biomedical applications. MOFs are usually electrical insulators (so as our expectation with bio-MOFs) and can be bestowed with reasonable electrical conductivity by the design. This discovery of electronically driven IMLT opens new opportunities for bio-MOFs, to emerge as strongly correlated reticular materials with thin film device functionalities.

Identifiers

PMID37208325
PMCPMC10198987

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.