ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2023
Leveraging Coupled Solvatofluorochromism and Fluorescence Quenching in Nitrophenyl-Containing Thiazolothiazoles for Efficient Organic Vapor Sensing.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed, 32 citations in OpenAlex.
- Electric field-dependent excited-state twisting in donor-acceptor thiazolothiazole dyes establishes a new class of cell membrane voltage sensors.Chemical science · 2026Article
- Synthesis and Solvatochromism of New Thiazole Derivatives Bearing N,N-Bis(2-methoxyethyl) Benzenesulfonamide Moiety.Journal of fluorescence · 2025Article
- Anion Association and Macrocycle Encapsulation Tune the Fluorescence ofOrganic letters · 2025Article
- Achieving Smart Photochromics Using Water-Processable, High-Contrast, Oxygen-Sensing, and Photoactuating Thiazolothiazole-Embedded Polymer Films.ACS applied optical materials · 2024Article
- Correlating structure and photophysical properties in thiazolo[5,4-Materials advances · 2023Article
- Leveraging Coupled Solvatofluorochromism and Fluorescence Quenching in Nitrophenyl-Containing Thiazolothiazoles for Efficient Organic Vapor Sensing.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
Corrections and comments
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Authors and funding
8 authors at 1 institution in 1 country.
Funding
Abstract
Solvatofluorochromic molecules provide strikingly high fluorescent outputs to monitor a wide range of biological, environmental, or materials-related sensing processes. Here, thiazolo[5,4-d]thiazole (TTz) fluorophores equipped with simple alkylamino and nitrophenyl substituents for solid-state, high-performance chemo-responsive sensing applications are reported. Nitroaromatic substituents are known to strongly quench dye fluorescence, however, the TTz core subtly modulates intramolecular charge transfer (ICT) enabling strong, locally excited-state fluorescence in non-polar conditions. In polar media, a planar ICT excited-state shows near complete quenching, enabling a twisted excited-state emission to be observed. These unique fluorescent properties (spectral shifts of 0.13 - 0.87 eV and large transition dipole moments Δµ = 20.4 - 21.3 D) are leveraged to develop highly sought-after chemo-responsive, organic vapor optical sensors. The sensors are developed by embedding the TTz fluorophores within a poly(styrene-isoprene-styrene) block copolymer to form fluorescent dye/polymer composites (Φ
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.