ReviewChemical reviews2023
Molecular Catalysis of Energy Relevance in Metal-Organic Frameworks: From Higher Coordination Sphere to System Effects.
Review in Chemical reviews, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
19 citing papers in PubMed, 108 citations in OpenAlex.
- Heterogeneous Indirect Redox Electrocatalysis in Electrolyte.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- Instability of PCN-224(Fe) during the oxygen reduction reaction; metal-organic framework electrocatalysts may have an Achilles heel.Chemical science · 2026Article
- Enzymatic Synthesis of Aroma Ester Catalyzed by Lipases Immobilized on Activated Carbon Derived from Fermented Cocoa Bean Shells.ACS omega · 2026Article
- Advancing biomedical technology through multifunctional porphyrin-based MOFs: design principles, applications, and biosafety evaluations.Materials today. Bio · 2026Review
- Cu-based metal-organic frameworks: synthesis, biomedical applications, and beyond.Discover nano · 2026Review
- Efficient and Robust Hybrid Molecular Photoanodes for Water Oxidation at Neutral pH Based on Ru Complexes Covalently Bonded to Polymeric Carbon Nitride.Artificial photosynthesis (Washington, D.C.) · 2026Article
- Surveying the Homogeneity of a Molecular Electrocatalyst Embedded in a Metal-Organic Framework Using Operando Characterization.ChemSusChem · 2025Article
- Solvent-Free Synthesis of Chiral SubstitutedACS omega · 2025Article
- 2D functionalized copper(ii)-carboxylate framework for efficient chemical fixation of carbon dioxide: insights from experimental and theoretical analysis.RSC advances · 2025Article
- Supramolecular Materials and Strategies for Bioorthogonal Chemical Transformations.Chemical reviews · 2025Review
- Node-Solution Microenvironment Governs the Selectivity of Thioanisole Oxidation within Catalytic Zr-Based Metal-Organic Framework.ACS applied materials & interfaces · 2025Article
- Switching between Limiting Charge Extraction Regimes in an Illuminated Semiconductor-Metal-Organic Framework Junction.Journal of the American Chemical Society · 2025Article
- The Role of Metal-Organic Framework Induced Confinement Effects on Molecular Electrocatalysts Relevant to the Energy Transition.ChemSusChem · 2025Review
- Diffusion-programmed catalysis in nanoporous material.Nature communications · 2025Article
- Mimic metalloenzymes with atomically dispersed Fe sites in covalent organic framework membranes for enhanced COChemical science · 2025Article
- Evaluating Nondestructive Quantification of Composition Gradients in Metal-Organic Frameworks by MeV Ion Microbeam Analysis.Analytical chemistry · 2024Article
- Supramolecular systems and their connection with metal-organic structures.Frontiers in chemistry · 2024Review
- Electrochromism in Isoreticular Metal-Organic Framework Thin Films with Record High Coloration Efficiency.ACS nano · 2023Article
- Engineering a molecular ruthenium catalyst into three-dimensional metal covalent organic frameworks for efficient water oxidation.Chemical science · 2023Article
Corrections and comments
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Authors and funding
7 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The modularity and synthetic flexibility of metal-organic frameworks (MOFs) have provoked analogies with enzymes, and even the term MOFzymes has been coined. In this review, we focus on molecular catalysis of energy relevance in MOFs, more specifically water oxidation, oxygen and carbon dioxide reduction, as well as hydrogen evolution in context of the MOF-enzyme analogy. Similar to enzymes, catalyst encapsulation in MOFs leads to structural stabilization under turnover conditions, while catalyst motifs that are synthetically out of reach in a homogeneous solution phase may be attainable as secondary building units in MOFs. Exploring the unique synthetic possibilities in MOFs, specific groups in the second and third coordination sphere around the catalytic active site have been incorporated to facilitate catalysis. A key difference between enzymes and MOFs is the fact that active site concentrations in the latter are often considerably higher, leading to charge and mass transport limitations in MOFs that are more severe than those in enzymes. High catalyst concentrations also put a limit on the distance between catalysts, and thus the available space for higher coordination sphere engineering. As transport is important for MOF-borne catalysis, a system perspective is chosen to highlight concepts that address the issue. A detailed section on transport and light-driven reactivity sets the stage for a concise review of the currently available literature on utilizing principles from Nature and system design for the preparation of catalytic MOF-based materials.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.