ArticleChemical science2023
On the existence of low-valent magnesium-calcium complexes.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
9 citing papers in PubMed, 33 citations in OpenAlex.
- C-H magnesiation of unactivated arenes by a bulky β-diketiminato magnesiumChemical science · 2026Article
- Comparison of MgYb and Mg-Ca bonding: structures, electronic analyses and reactivities.Chemical science · 2026Article
- Magnesium(0) complexes and their reduction reactions with binary transition metal carbonyls.Chemical science · 2026Article
- A Modular Approach to Asymmetric Mg(I) Complexes Using a Unique Cyclopentadienyl Mg(I) Complex.Angewandte Chemie (International ed. in English) · 2025Article
- Syntheses and Reactivity of Yb and Sm Inverse Sandwich Arene Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dinitrogen Activation with Low-Valent Strontium.Angewandte Chemie (International ed. in English) · 2025Article
- Heavy Alkaline Earth Cyclic (Alkyl)(Amino)Carbene Complexes Supported by Aryl-Silyl Amides.Inorganic chemistry · 2024Article
- Cooperative activation of carbon-hydrogen bonds by heterobimetallic systems.Dalton transactions (Cambridge, England : 2003) · 2024Review
- A Blueprint for the Stabilization of Sub-Valent Alkaline Earth Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
DFT-Calculations predict that a low-valent complex (BDI)Mg-Ca(BDI) with bulky β-diketiminate (BDI) ligands is thermodynamically stable. It was attempted to isolate such a complex by salt-metathesis between [(
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.