Evidence map›Paper›PMID 37177207›Full record

ArticlePolymers2023

Ultramicroporous Polyphenylenes via Diels-Alder Polycondensation Approach.

Svetlana A Sorokina, Nina V Kuchkina, Alexander V Mikhalchenko, Irina Yu Krasnova, Dmitry A Khanin, Kirill M Skupov, Zinaida B Shifrina

Abstract read
In one paragraph

Article in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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3 · Its place in the literature

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4 · The record

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5 · Who and what money

Authors and funding

7 authors.

Svetlana A SorokinaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., 119991 Moscow, Russia.ORCID 0009-0001-8286-5379
Nina V KuchkinaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., 119991 Moscow, Russia.ORCID 0000-0001-5838-8907
Alexander V MikhalchenkoA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., 119991 Moscow, Russia.
Irina Yu KrasnovaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., 119991 Moscow, Russia.
Dmitry A KhaninA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., 119991 Moscow, Russia.
Kirill M SkupovA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., 119991 Moscow, Russia.ORCID 0000-0001-8255-2113
Zinaida B ShifrinaA.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov St., 119991 Moscow, Russia.

Funding

Russian Science Foundation 22-73-00087
6 · The paper itself

Abstract

Development of new microporous organic polymers attracts significant attention due to a wide scope of promising applications. In addition, the synthesis of soluble, non-crosslinking polymers of high surface area and uniform microporosity is very challenging, and the methods for soluble microporous polymers formation are rather limited. In this work, we report a new approach to construct porous polyphenylenes which employs the Diels-Alder polycondensation of multifunctional ethynyl-containing monomers of different spatial architecture with bis(cyclopentadienone)s. The resulting polymers were soluble in common organic solvents, and their structure and properties were assessed by NMR, TGA, DSC, and SEC studies. The polymers demonstrated a specific surface area up to 751 m

Indexed as

Diels–Alder reactionmicroporous non-network polymerspolyphenylenesporous organic polymers (POPs)solution processability

Identifiers

PMID37177207
PMCPMC10181309

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