ArticleNature communications2023
[2,2] Paracyclophanes-based double helicates for constructing artificial light-harvesting systems and white LED device.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed, 65 citations in OpenAlex.
- Synthesis and Properties of Optically Active X-Shaped Compounds With Electron-Withdrawing Groups Based on Planar Chiral [2.2]Paracyclophane.Chemistry, an Asian journal · 2026Article
- Phase transfer-driven formation of solid metal-organic materials with tunable optical and adsorption properties.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- Construction of planar chiral [2,2]paracyclophanes via photoinduced cobalt-catalyzed desymmetric addition.Nature communications · 2025Article
- Artificial light harvesting systems based on novel AIEgen-branched rotaxane dendrimers for photocatalyzed functionalization of C-H bonds.Chemical science · 2025Article
- Supramolecular rosette intermediated homochiral double helix.Nature communications · 2025Article
- Synthesis of optically active folded cyclic dimers and trimers.Beilstein journal of organic chemistry · 2025Article
- Multi-Step and Switchable Energy Transfer in Photoluminescent Organosilicone Capsules.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- New multiple-layered 3D polymers showing aggregation-induced emission and polarization.RSC advances · 2024Article
- Multi-step FRET systems based on discrete supramolecular assemblies.Communications chemistry · 2024Review
- Article
- Controlling aggregation-induced emission by supramolecular interactions and colloidal stability in ionic emitters for light-emitting electrochemical cells.Chemical science · 2024Article
- Efficient manipulation of Förster resonance energy transfer through host-guest interaction enables tunable white-light emission and devices in heterotopic bisnanohoops.Chemical science · 2023Article
- An artificial light-harvesting system constructed from a water-soluble metal-organic barrel for photocatalytic aerobic reactions in aqueous media.Chemical science · 2023Article
Corrections and comments
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Authors and funding
6 authors at 1 institution in 1 country.
Funding
Abstract
The construction of efficient artificial light-harvesting systems (ALHSs) is of vital importance in utilizing solar energy. Herein, we report the non-covalent syntheses of double helicates PCP-TPy1/2 and Rp,Rp-PCP-TPy1/2 by metal-coordination interaction and their applications in ALHSs and white light-emitting diode (LED) device. All double helicates exhibit significant aggregation-induced emission in tetrahydrofuran/water (1:9, v/v) solvent. The aggregated double helicates can be used to construct one-step or sequential ALHSs with fluorescent dyes Eosin Y (EsY) and Nile red (NiR) with the energy transfer efficiency up to 89.3%. Impressively, the PMMA film of PCP-TPy1 shows white-light emission when doped 0.075% NiR, the solid of double helicates (Rp,Rp-) PCP-TPy2 can be used as the additive of a blue LED bulb to achieve white-light emission. In this work, we provided a general method for the preparation of novel double helicates and explored their applications in ALHSs and fluorescent materials, which will promote future construction and application of helicates as emissive devices.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.