ArticleACS catalysis2022
(CAAC)Copper Catalysis Enables Regioselective Three-Component Carboboration of Terminal Alkynes.
Article in ACS catalysis, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Programmable alkene skeleton construction via switchable radical and organometallic sorting.Nature chemistry · 2026Article
- Three-Component 1,2-Methylamidation of Alkynes via Coordinating Activation Strategy.ChemistryOpen · 2025Article
- Transition-Metal-Free Thioboration of Terminal Alkynes.JACS Au · 2024Article
- Ring-Expanded N-Heterocyclic Carbene (reNHC) Complexes: Applications in Transition Metal Catalysis.Coordination chemistry reviews · 2024Article
- Copper-Metallized Porous N-Heterocyclic Carbene Ligand Polymer-Catalyzed Regio- and Stereoselective 1,2-Carboboration of Alkynes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Catalytic Alkyne Allylboration: A Quest for Selectivity.ACS catalysis · 2023Review
- Updated Progress of the Copper-Catalyzed Borylative Functionalization of Unsaturated Molecules.Molecules (Basel, Switzerland) · 2023Review
- Regioselective catalytic carbonylation and borylation of alkynes with aryldiazonium salts toward α-unsubstituted β-boryl ketones.Chemical science · 2022Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
Cyclic(alkyl)(amino)carbene (CAAC) ligands are found to perturb regioselectivity of the copper-catalyzed carboboration of terminal alkynes, favoring the less commonly observed internal alkenylboron regiosomer through an α-selective borylcupration step. A variety of carbon electrophiles participate in the reaction, including allyl alcohols derivatives and alkyl halides. The method provides a straightforward and selective route to versatile tri-substituted alkenylboron compounds that are otherwise challenging to access.
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Registered trials
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