ArticleNature communications2023
Rhodium nanoparticles supported on silanol-rich zeolites beyond the homogeneous Wilkinson's catalyst for hydroformylation of olefins.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 87 citations in OpenAlex.
- Beyond Dealumination: Does Fluorine Reshape Zeolitic Acidity?Journal of the American Chemical Society · 2026Article
- Circumventing the wettability issue of heterogeneous metal catalysts for solvent-free organic transformations.Nature communications · 2026Article
- Molecule-well in platinum-zeolite engineers molecular adsorption for highly selective hydrogenation.Nature communications · 2026Article
- Unmasking true confinement effects: ultrahigh linear selectivity and chain-length oscillatory behavior in zeolite-encapsulated rhodium hydroformylation.National science review · 2026Article
- Nonequilibrium pulsed heating freezes sintering of supported metal nanocatalysts.Nature communications · 2026Article
- Synergistic Catalysis and Sensing: Oxacalix[4]arene-Stabilized Rhodium Nanoparticles for Dye Degradation, Nitroaromatic Reduction and Al³⁺ Ion Detection.Journal of fluorescence · 2025Article
- Tungsten Species on Beta Zeolite with Abundant Silanol Nests for Efficient Olefin Metathesis.Chem & bio engineering · 2025Article
- Boosting Hydroformylation via Reactant Enrichment in Covalent Triazine Frameworks with Atomically Dispersed Rh.Materials (Basel, Switzerland) · 2025Article
- Low-Temperature Exsolution of Rh from Mixed ZnFeRh Oxides toward Stable and Selective Catalysts in Liquid-Phase Hydroformylation.Journal of the American Chemical Society · 2025Article
- Synergy of pore size and silanols in an -SVR-type zeolite for efficient dynamic benzene/cyclohexane separation.Nature communications · 2024Article
- Elucidation of hemilabile-coordination-induced tunable regioselectivity in single-site Rh-catalyzed heterogeneous hydroformylation.Nature communications · 2024Article
Corrections and comments
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Authors and funding
13 authors at 5 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Hydroformylation is one of the largest industrially homogeneous processes that strongly relies on catalysts with phosphine ligands such as the Wilkinson's catalyst (triphenylphosphine coordinated Rh). Heterogeneous catalysts for olefin hydroformylation are highly desired but suffer from poor activity compared with homogeneous catalysts. Herein, we demonstrate that rhodium nanoparticles supported on siliceous MFI zeolite with abundant silanol nests are very active for hydroformylation, giving a turnover frequency as high as ~50,000 h
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Registered trials
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