ArticleAngewandte Chemie (International ed. in English)2023
Alkali Metal Dihydropyridines in Transfer Hydrogenation Catalysis of Imines: Amide Basicity versus Hydride Surrogacy.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Calcium Alkynyl(hydrido)zincates.Organometallics · 2026Article
- Comparisons and Contrasts in a Complete Set of Alkali Metal Cumyl Structures.Inorganic chemistry · 2026Article
- Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation.Angewandte Chemie (International ed. in English) · 2026Article
- COJournal of the American Chemical Society · 2025Article
- Heavyweight Champion: Caesium Diorganophosphides Outperform Lighter Congeners in the Catalytic Hydrophosphination of Alkenes and Alkynes.Angewandte Chemie (International ed. in English) · 2025Article
- Isomeric Effects in Lithium Dihydropyridinate Chemistry: The Privileged Status of the tert-Butyl Isomer.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates.Organometallics · 2024Article
- Synthesis, characterisation, and catalytic application of a soluble molecular carrier of sodium hydride activated by a substituted 4-(dimethylamino)pyridine.Communications chemistry · 2024Article
- Alkali Metal Dihydropyridines in Transfer Hydrogenation Catalysis of Imines: Amide Basicity versus Hydride Surrogacy.Angewandte Chemie (International ed. in English) · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
Abstract
Catalytic reduction of a representative set of imines, both aldimines and ketimines, to amines has been studied using transfer hydrogenation from 1,4-dicyclohexadiene. Unusually, this has been achieved using s-block pre-catalysts, namely 1-metallo-2-tert-butyl-1,2-dihydropyridines, 2-tBuC
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