ReviewNature reviews. Chemistry2020
Bimetallic cooperation across the periodic table.
Review in Nature reviews. Chemistry, 2020. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 69 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
69 citing papers in PubMed.
- Silicon-Bridged Homocyclopentadienides: Metal-Assisted Facile Ring Expansion of Cyclopentadienide by Transient Imino(Metallophosphino)Silylenes.Angewandte Chemie (International ed. in English) · 2026Article
- Lewis Acid/Base Au-Mn Pairs in Metal Nanoclusters for Enhanced Photocatalytic C(spAngewandte Chemie (International ed. in English) · 2026Article
- Formation of Gallium Monofluoride in the Coordination Sphere of Nickel.Angewandte Chemie (International ed. in English) · 2026Article
- Protonation-Induced Electron Density Redistribution Facilitates Aggregation in PNNP Dicopper Hydride Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Long-range metal-metal cooperative nitrile activation in 1,8-diazaanthracene-supported dicopper complexes.Chemical communications (Cambridge, England) · 2026Article
- Entropy-Driven Ligand Exchange in a Rotationally Flexible Dinuclear Fe(II)-Fe(II) Complex.Inorganic chemistry · 2026Article
- Metal-defect pairs for near-stoichiometric electrocatalytic C-N coupling.National science review · 2026Article
- Manganese(II) and Magnesium(II) Analogies in Iridium Hydride Coordination Chemistry.Inorganic chemistry · 2026Article
- Diiron(I) Bis(cyclopentadienyl) Complexes with Bridging Iminium Ligands: From Foundational Organometallic Chemistry to Unique Reactivity and Biological Potential.Accounts of chemical research · 2026Article
- Phyto-synthesized silver-iron oxide nanoparticles fromFrontiers in chemistry · 2026Article
- Snapshots of Cooperative Trimetallic Alkene Hydrogenation.Journal of the American Chemical Society · 2025Article
- Phthalocyanine-based covalent organic frameworks: bridging molecular design and catalytic performance in CORSC advances · 2025Review
- Probing Structural Diversity in a Series of Perhydrocarbyl Heterobimetallic Complexes Associating Tantalum and 3d (Cr, Mn, Fe, Co, Ni) Transition Metals.Inorganic chemistry · 2025Article
- Alkyne Dihydroboration viaJournal of the American Chemical Society · 2025Article
- Sequential one-potChemical science · 2025Article
- Recent Advances in Heterogeneous Hydroformylation at Metal-Oxide Interfaces.Molecules (Basel, Switzerland) · 2025Review
- Heterobinuclear Molecular Precursors Direct the Formation of Supported Subnanometer Cu-M Clusters with Tunable Catalytic Behavior.ACS applied materials & interfaces · 2025Article
- Artificial Chiral Trinuclear Zn Catalysts: Design, Self-Assembly and Unprecedented Efficiency in Asymmetric Hydroboration of Ketones.ACS central science · 2025Article
- Computational Characterization of Unsupported Au(I)···Ir(I) Metallophilic Interactions: Evidence for Strong Dispersive Stabilization.Inorganic chemistry · 2025Article
- A non-metal-to-metal INature communications · 2025Article
9 more citing papers are in PubMed but not listed here.
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
1 author.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Organometallic chemistry and its applications in homogeneous catalysis have been dominated by mononuclear transition-metal complexes. The catalytic performance and physico-chemical properties of these mononuclear complexes can be rationally tuned by ligand modification, which has also led to the discovery of new reactions. There is a growing body of evidence implicating the participation of two metals in catalytic processes originally believed to follow monometallic mechanisms. Moreover, the deliberate preparation of bimetallic structures has proven popular because these preorganized structures have many tunable features, such as metal-metal bond order and polarity. These structures can exhibit metal-metal complementarity and allow for multisite activation - reactivity unattainable with truly mononuclear species. This Perspective summarizes the features that are exclusive to bimetallic systems and their roles in substrate activation.
Identifiers
37127975What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.