ArticleThe journal of physical chemistry. A2023
Low-Temperature Gas-Phase Kinetics of Ethanol-Methanol Heterodimer Formation.
Article in The journal of physical chemistry. A, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Experimental and Theoretical Study of the Kinetics of Dimerization of Ammonia at Low Temperatures.The journal of physical chemistry. A · 2025Article
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7 authors.
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Abstract
The structures of gas-phase noncovalently bound clusters have long been studied in supersonic expansions. This method of study, while providing a wealth of information about the nature of noncovalent bonds, precludes observation of the formation of the cluster, as the clusters form just after the orifice of the pulsed valve. Here, we directly observe formation of ethanol-methanol dimers via microwave spectroscopy in a controlled cryogenic environment. Time profiles of the concentration of reagents in the cell yielded gas-phase reaction rate constants of
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