ReviewNature reviews. Chemistry2021
Charge frustration in ligand design and functional group transfer.
Review in Nature reviews. Chemistry, 2021. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
9 citing papers in PubMed.
- Backbone Engineering of Carbon-Centered NHC-Derived Diradicals: From Electronic State Tuning to High-Performance Organic Field-Effect Transistors.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Flash Communication: (PhOrganometallics · 2026Article
- Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025Article
- A Lead(II) Substituted Triplet Carbene.Journal of the American Chemical Society · 2024Article
- Gauging Radical Stabilization with Carbenes.Angewandte Chemie (International ed. in English) · 2022Article
- An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes.Angewandte Chemie (International ed. in English) · 2022Article
- A New Class of Task-Specific Imidazolium Salts and Ionic Liquids and Their Corresponding Transition-Metal Complexes for Immobilization on Electrochemically Active Surfaces.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Accessing Cationic α-Silylated and α-Germylated Phosphorus Ylides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- A Zwitterionic Heterobimetallic Gold-Iron Complex Supported by Bis(N-Heterocyclic Imine)Silyliumylidene.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Molecules with different resonance structures of similar importance, such as heterocumulenes and mesoionics, are prominent in many applications of chemistry, including 'click chemistry', photochemistry, switching and sensing. In coordination chemistry, similar chameleonic/schizophrenic entities are referred to as ambidentate/ambiphilic or cooperative ligands. Examples of these had remained, for a long time, limited to a handful of archetypal compounds that were mere curiosities. In this Review, we describe ambiphilicity - or, rather, 'charge frustration' - as a general guiding principle for ligand design and functional group transfer. We first give a historical account of organic zwitterions and discuss their electronic structures and applications. Our discussion then focuses on zwitterionic ligands and their metal complexes, such as those of ylidic and redox-active ligands. Finally, we present new approaches to single-atom transfer using cumulated small molecules and outline emerging areas, such as bond activation and stable donor-acceptor ligand systems for reversible 1e
Identifiers
37118028What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.