ReviewNature reviews. Chemistry2023
Prospects and challenges for nitrogen-atom transfer catalysis.
Review in Nature reviews. Chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- A photogenerated triplet aura-nitrene for gold-mediated nitrene transfer.Nature chemistry · 2026Article
- A gold nitrene for nitrogen-atom transfer chemistry.Nature chemistry · 2026Article
- Highly Stable Mn(V)-Nitrido and Nitrogen-Atom Transfer Reactivity within aJournal of the American Chemical Society · 2026Article
- Methane Catalytic Amidation via a Plausible Copper-Nitrene Intermediate.Journal of the American Chemical Society · 2026Article
- X-ray activated platinum complex induces DNA damage and enhances cancer immunotherapy through abscopal effect.Nature biomedical engineering · 2026Article
- Isolation of a Terminal Cobalt Nitride in a Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
- Exploring osteosarcopenia from the gut microbiota perspective: mechanistic insights and therapeutic potentials based on the gut-muscle-bone Axis.Frontiers in microbiology · 2026Review
- Nitrene-mediated aminative N-N-N coupling: facile access to triazene 1-oxides.Chemical science · 2025Article
- P-P CouplingJournal of the American Chemical Society · 2025Article
- Redox-Tunable Ring Expansion Enabled By A Single-Component Electrophilic Nitrogen Atom Synthon.Angewandte Chemie (International ed. in English) · 2025Article
- An Open-Shell FeJournal of the American Chemical Society · 2025Article
- Exploring the Relationship Between Gut Microbiota and Sarcopenia Based on Gut-Muscle Axis.Food science & nutrition · 2024Review
- Article
- Bonding and Reactivity of dJournal of the American Chemical Society · 2024Article
- Untangling ancillary ligand donationChemical science · 2024Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Conversion of C-H bonds to C-N bonds via C-H amination promises to streamline the synthesis of nitrogen-containing compounds. Nitrogen-group transfer (NGT) from metal nitrenes ([M]-NR complexes) has been the focus of intense research and development. By contrast, potentially complementary nitrogen-atom transfer (NAT) chemistry, in which a terminal metal nitride (an [M]-N complex) engages with a C-H bond, is underdeveloped. Although the earliest examples of stoichiometric NAT chemistry were reported 25 years ago, catalytic protocols are only now beginning to emerge. Here, we summarize the current state of the art in NAT chemistry and discuss opportunities and challenges for its development. We highlight the synthetic complementarity of NGT and NAT and discuss critical aspects of nitride electronic structure that dictate the philicity of the metal-supported nitrogen atom. We also examine the characteristic reactivity of metal nitrides and present emerging strategies and remaining obstacles to harnessing NAT for selective, catalytic nitrogenation of unfunctionalized organic small molecules.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.