ReviewNature reviews. Chemistry2022
Energy- and atom-efficient chemical synthesis with endergonic photocatalysis.
Review in Nature reviews. Chemistry, 2022. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
22 citing papers in PubMed.
- Iontrovoltaic effect based on triboelectrically induced ion polarization at semiconductor-liquid interfaces.Nature communications · 2026Article
- White-light powered autonomous molecular ratchet drives PdChemical science · 2026Article
- Enantioselective Contrathermodynamic Olefin Isomerization.Journal of the American Chemical Society · 2026Article
- Evolution of manganese low-energy photoredox catalysis from high-energy visible light photocatalysis.Nature communications · 2026Article
- Dual Semiconductor-Photoredox/Halogen-Bonding Organocatalyzed Cascade Sulfonylation/Cyclization of Alkynes and Alkenes with RSOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Deazaalloxazines - Flavin Derivatives That Provide Reductive Photoredox Catalysis with Inert Substrates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Harnessing Photochemistry in Natural Product Synthesis: From Strategy to Applications.Journal of natural products · 2025Review
- Fully Sensitized Upconversion Nanoparticles as Efficient Catalysts for NIR-Driven UV Photochemistry.Angewandte Chemie (International ed. in English) · 2025Article
- Photocatalytic streamlined dual-functional group transfer from cyanopyridine to internal alkynes.Nature communications · 2025Article
- Enantioselective Photochemical Generation of a Short-Lived, Twisted Cycloheptenone Isomer: Catalytic Formation, Detection, and Consecutive Chemistry.Angewandte Chemie (International ed. in English) · 2025Article
- Kinetic Analysis of the Redox-Neutral Catalytic Mitsunobu Reaction: Dehydration, Kinetic Barriers, and Hopping between Potential Energy Surfaces.Journal of the American Chemical Society · 2025Article
- Artificial photosynthesis directed toward organic synthesis.Nature communications · 2025Article
- Light-enabled intramolecular [2 + 2] cycloaddition via photoactivation of simple alkenylboronic esters.Beilstein journal of organic chemistry · 2025Article
- Integrating CuMaterials (Basel, Switzerland) · 2024Article
- Enantioselective Cobaltaphotoredox-Catalyzed C-H Activation.Journal of the American Chemical Society · 2024Article
- Enhancing Performance of Organic Pollutant Degradation via Building Heterojunctions with ZnO Nanowires and Na Doped Conjugated 2,4,6-Triaminopyrimidin-g-CMolecules (Basel, Switzerland) · 2024Article
- Organic Synthesis Away from Equilibrium: Contrathermodynamic Transformations Enabled by Excited-State Electron Transfer.Accounts of chemical research · 2024Article
- Intracellular Synthesis of Indoles Enabled by Visible-Light Photocatalysis.Journal of the American Chemical Society · 2024Article
- Ratcheting synthesis.Nature reviews. Chemistry · 2024Review
- Ring opening of photogenerated azetidinols as a strategy for the synthesis of aminodioxolanes.Beilstein journal of organic chemistry · 2024Article
Corrections and comments
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Endergonic photocatalysis is the use of light to perform catalytic reactions that are thermodynamically unfavourable. While photocatalysis has become a powerful tool in facilitating chemical transformations, the light-energy efficiency of these processes has not gathered much attention. Exergonic photocatalysis does not take full advantage of the light energy input, producing low-energy products and heat, whereas endergonic photocatalysis incorporates a portion of the photon energy into the reaction, yielding products that are higher in free energy than the reactants. Such processes can enable catalytic, atom-economic syntheses of reactive compounds from bench-stable materials. With respect to environmental friendliness and carbon neutrality, endergonic photocatalysis is also of interest to large-scale industrial manufacturing, where better energy efficiency, less waste and value addition are highly sought. We therefore assess here the thermochemistry of several classes of reported photocatalytic transformations to showcase current advances in endergonic photocatalysis and point to their industrial potential.
Identifiers
37117495What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.