ArticleNature communications2023
Atomically precise gold nanoclusters at the molecular-to-metallic transition with intrinsic chirality from surface layers.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Advances and Prospects of Chiral Plasmonic Nanomaterials in Emerging Applications.Nanomaterials (Basel, Switzerland) · 2026Review
- Ligand-Tuned CISS-Effect of Atomically Precise Metal Oxido Nanoclusters.The journal of physical chemistry letters · 2026Article
- Ligand-Induced Structural Evolution and Luminescence Tuning in a Series of Superatomic Ir/Ag Hydride-Containing Nanoclusters.Inorganic chemistry · 2026Article
- Chirality Transfer in Gold Nanoclusters: Insights from Chiral Spectroscopy and Theoretical Modeling.ACS physical chemistry Au · 2026Article
- Co-Reactant Engineering for Au Nanocluster Electrochemiluminescence.Molecules (Basel, Switzerland) · 2025Review
- Sub-ångström bond length tuning enhances photoluminescence quantum yield in copper nanoclusters.Nature communications · 2025Article
- Vibrational Circular Dichroism Spectra of Atomically-Precise Metal Clusters: Unveiling Conformational Structures and Mechanism of VCD Enhancement via Full Models.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Rational Design and Applications of Ultrasmall Gold Nanoparticles.Topics in current chemistry (Cham) · 2025Review
- Article
- Remove the innermost atom of a magnetic multi-shell gold nanoparticle for near-unity conversion of COScience advances · 2025Article
- Symmetrical and asymmetrical surface structure expansions of silver nanoclusters with atomic precision.Chemical science · 2025Article
- Silvery fullerene in AgNational science review · 2024Article
- NIR-II emissive anionic copper nanoclusters with intrinsic photoredox activity in single-electron transfer.Nature communications · 2024Article
- Dynamic surface reconstruction of individual gold nanoclusters by using a co-reactant enables color-tunable electrochemiluminescence.Chemical science · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
The advances in determining the total structure of atomically precise metal nanoclusters have prompted extensive exploration into the origins of chirality in nanoscale systems. While chirality is generally transferrable from the surface layer to the metal-ligand interface and kernel, we present here an alternative type of gold nanoclusters (138 gold core atoms with 48 2,4-dimethylbenzenethiolate surface ligands) whose inner structures are not asymmetrically induced by chiral patterns of the outermost aromatic substituents. This phenomenon can be explained by the highly dynamic behaviors of aromatic rings in the thiolates assembled via π - π stacking and C - H···π interactions. In addition to being a thiolate-protected nanocluster with uncoordinated surface gold atoms, the reported Au
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Registered trials
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