ArticleACS sustainable chemistry & engineering2023
Vanillin-Based Epoxy Vitrimers: Looking at the Cystamine Hardener from a Different Perspective.
Article in ACS sustainable chemistry & engineering, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
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Who cites it
16 citing papers in PubMed.
- UV Curing of Biobased Electrically Conductive Coatings with Covalent Adaptable Network Properties.Polymers · 2026Article
- Machinability of Vitrified Semi-Finished Products: Chip Formation and Heat Development at the Cutting Edge.Polymers · 2025Article
- Discovery of powerful multifaceted antioxidant for combating oxidative stress associated with neurodegenerative disorders.Acta pharmaceutica Sinica. B · 2025Article
- Thermoset Polyester Resin Microplastics: Effects on Enzymatic Biomarkers and Toxicological Endpoint Responses ofToxics · 2025Article
- Solvent-Free Synthesis of Closed-Loop Recyclable Acetal Thermosets Derived from Biobased Resources.ChemSusChem · 2025Article
- How to Characterize Covalent Adaptable Networks: A User Guide.ACS polymers Au · 2025Article
- Qualification of the Vitrimeric Matrices in Industrial-Scale Wet Filament Winding Processes for Type-4 Pressure Vessels.Polymers · 2025Article
- Taking dynamic covalent chemistry out of the lab and into reprocessable industrial thermosets.Nature reviews. Chemistry · 2025Review
- Precise Carboxylic Acid-Functionalized Polyesters in Reprocessable Vitrimers.Journal of the American Chemical Society · 2025Article
- Current State-of-the-Art and Perspectives in the Design and Application of Vitrimeric Systems.Molecules (Basel, Switzerland) · 2025Review
- Innovative Materials Based on Epoxy Resin for Use as Seat Elements in Bulk Transport.Materials (Basel, Switzerland) · 2024Article
- A Biobased Epoxy Vitrimer with Dual Relaxation Mechanism: A Promising Material for Renewable, Reusable, and Recyclable Adhesives and Composites.ACS sustainable chemistry & engineering · 2024Article
- Covalent Adaptable Networks with Tailorable Material Properties Based on Divanillin Polyimines.Biomacromolecules · 2024Article
- Reductive amination cascades in cell-free and resting whole cell formats for valorization of lignin deconstruction products.Biotechnology and bioengineering · 2024Article
- On a Biobased Epoxy Vitrimer from a Cardanol Derivative Prepared by a Simple Thiol-Epoxy "Click" Reaction.ACS omega · 2024Article
- Analysis of the Effect of Network Structure and Disulfide Concentration on Vitrimer Properties.Polymers · 2023Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Epoxy vitrimers encompass many advantages compared to traditional epoxy materials such as recyclability, repairability, and reprocessability. These properties are induced by the incorporation of dynamic reversible covalent bonds. Recently, the incorporation of aromatic disulfide bridges that are dynamic has expanded the development of new eco-friendly epoxy materials. Herein, we studied a bio-based aliphatic disulfide based on cystamine as a hardener with a vanillin-derived bio-sourced epoxy to prepare fully bio-based epoxy vitrimers. This article provides a comparative study between cystamine and an aromatic disulfide benchmark hardener issued from petrol resources. This work demonstrated that the presence of this aliphatic hardener has a significant influence not only on the reactivity, but most importantly on the resulting dynamic properties. An interesting yet counterintuitive accelerating effect of the dynamic exchanges was clearly demonstrated with only 2 to 20% of molar fraction of cystamine added to the aromatic disulfide formulation. A similar glass transition was obtained compared to the purely aromatic analogue, but relaxation times were decreased by an order of magnitude.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.