Evidence map›Paper›PMID 37086176›Full record

ArticleJournal of the American Chemical Society2023

Catalytic Asymmetric Cyclopropanations with Nonstabilized Carbenes.

Kristen E Berger, Raymond J Martinez, Jianhan Zhou, Christopher Uyeda

Open access · greenAbstract read
In one paragraph

Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.

0numbers the graph read from it
0cells of the map it votes in
21citing papers in PubMed
11.8field-weighted citation impact, top 1% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

21 citing papers in PubMed, 79 citations in OpenAlex.

  1. Article
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  5. Article
  6. Review
  7. Article
  8. Copper-CatalyzedThe Journal of organic chemistry · 2026
    Article
  9. Article
  10. Article
  11. Article
  12. Article
  13. Article
  14. Article
  15. Cyclopropanation with Non-Stabilized Carbenes via Ketyl Radicals.Journal of the American Chemical Society · 2024
    Article
  16. Reductive Cyclopropanation through Bismuth Photocatalysis.Journal of the American Chemical Society · 2024
    Article
  17. Article
  18. Redox Approaches to Carbene Generation in Catalytic Cyclopropanation Reactions.Angewandte Chemie (International ed. in English) · 2024
    Review
  19. Review
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 1 institution in 2 countries.

Kristen E BergerDepartment of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States.ORCID 0000-0001-5723-6661
Raymond J MartinezDepartment of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States.
Jianhan ZhouDepartment of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States.
Christopher UyedaDepartment of Chemistry, Purdue University, 560 Oval Drive, West Lafayette, Indiana 47907, United States.ORCID 0000-0001-9396-915X
Purdue University West Lafayette · US

Funding

Transition Metal Catalyzed Reductive Carbene Transfer ReactionsR35GM124791 · NIGMS · PURDUE UNIVERSITY · PI Christopher Uyeda · 2017 to 2026
$4.2M
NIGMS NIH HHS R35 GM124791
6 · The paper itself

Abstract

Cyclopropanes are common building blocks in pharmaceuticals, agrochemicals, and organic materials. The most general methods for the synthesis of chiral cyclopropanes are catalytic additions of diazoalkanes to alkenes. However, a limitation of this approach is that diazoalkanes can only be safely handled on preparative scales if they possess stabilizing substituents. Here we show that

Identifiers

PMID37086176
PMCPMC10226076
OpenAlexW4366742641

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.