ArticleAngewandte Chemie (International ed. in English)2023
An Electrochemical Strategy to Synthesize Disilanes and Oligosilanes from Chlorosilanes.
Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- SmIChemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Electrochemically deuterated silane synthesis with DScience advances · 2026Article
- A DMAP-enabled strategy for C(spNature communications · 2025Article
- Deoxygenative Cyanofunctionalization of Aldehydes and Ketones Enabled by Electrochemical Reduction.Journal of the American Chemical Society · 2025Article
- Article
- Electrochemical synthesis of allenyl silanes and allenyl boronic esters.Nature communications · 2025Article
- Cross-Electrophile Coupling: Principles, Methods, and Applications in Synthesis.Chemical reviews · 2024Review
- Electrochemical Glycosylation via Halogen-Atom-Transfer forACS catalysis · 2024Article
- Electroreduction of unactivated alkenes using water as hydrogen source.Nature communications · 2024Article
- Ligand Relay for Nickel-Catalyzed Decarbonylative Alkylation of Aroyl Chlorides.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Electroreductive Radical Addition-Polar Cyclization Cascade to Access Cycloalkanes.Organic letters · 2024Article
- Enabling Al sacrificial anodes in tetrahydrofuran electrolytes for reductive electrosynthesis.Chemical science · 2023Article
- Disilane-bridged architectures: an emerging class of molecular materials.Chemical science · 2023Review
- Deep Electroreductive Chemistry: Harnessing Carbon- and Silicon-based Reactive Intermediates in Organic Synthesis.ACS catalysis · 2023Article
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8 authors.
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Abstract
Silanes are important compounds in industrial and synthetic chemistry. Here, we develop a general approach for the synthesis of disilanes as well as linear and cyclic oligosilanes via the reductive activation of readily available chlorosilanes. The efficient and selective generation of silyl anion intermediates, which are arduous to achieve by other means, allows for the synthesis of various novel oligosilanes by heterocoupling. In particular, this work presents a modular synthesis for a variety of functionalized cyclosilanes, which may give rise to materials with distinct properties from linear silanes but remain challenging synthetic targets. In comparison to the traditional Wurtz coupling, our method features milder conditions and improved chemoselectivity, broadening the functional groups that are compatible in oligosilane preparation. Computational studies support a mechanism whereby differential activation of sterically and electronically distinct chlorosilanes are achieved in an electrochemically driven radical-polar crossover mechanism.
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