ReviewScience advances2023
Transition metal-catalyzed remote C─H borylation: An emerging synthetic tool.
Review in Science advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
21 citing papers in PubMed.
- Group 4 Metallocenes Supported on Sulfated Zirconium Oxide Catalyze Benzene C-H Borylation.Journal of the American Chemical Society · 2026Article
- Highly Active CH Bond Borylation of Aromatics With Pyridine as Convenient, Low-Cost Ligand Under Iridium Catalysis.ChemSusChem · 2026Article
- Regioselective Arene C-H Borylation with a MOF-Immobilized Iridium Bipyridine Catalyst.ACS applied materials & interfaces · 2026Article
- Triazine-based cobalt pincer complex for regioselective C-H borylation of furans.Scientific reports · 2026Article
- Iridium catalyzed regiodivergent functionalization of all three C-H bonds of arenes by a single ligand.Nature communications · 2025Article
- Arene Ruthenium(II) Carboxylates for C─H Alkylations and Arylations at Near Room Temperature.Angewandte Chemie (International ed. in English) · 2025Article
- Enantioselective Miyaura Reaction by Desymmetrizing C(spAngewandte Chemie (International ed. in English) · 2025Article
- COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Alkene Borylation-Hydrogenation Enables Highly Active, Site-Selective Cobalt-Catalyzed Borylation.Journal of the American Chemical Society · 2025Article
- Copper-Catalyzed Regioselective Meta C─H Bond Olefination of Anilides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Bis-CFACS catalysis · 2025Article
- Controlling the Symmetry of Perylene Derivatives via SelectiveThe Journal of organic chemistry · 2025Article
- High-Throughput Enabled Iridium-Catalyzed C-H Borylation Platform for Late-Stage Functionalization.ACS catalysis · 2025Article
- Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(Nature catalysis · 2025Article
- Article
- Repurposing a supramolecular iridium catalystChemical science · 2024Article
- Leveraging Language Model Multitasking To Predict C-H Borylation Selectivity.Journal of chemical information and modeling · 2024Article
- Catalyst Design for Rh-Catalyzed Arene and Alkane C-H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp.Organometallics · 2024Article
- Noncovalent interaction with a spirobipyridine ligand enables efficient iridium-catalyzed C-H activation.Nature communications · 2024Article
- Trialkoxysilane-Induced Iridium-Catalyzed para-Selective C-H Bond Borylation of Arenes.Nature communications · 2024Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Transition metal-catalyzed C─H bond activation and borylation is a powerful synthetic method that offers versatile synthetic transformation from organoboron compounds to virtually all other functional groups. Compared to the ortho-borylation, remote borylation remains more challenging owing to the inaccessibility of these C─H bonds. Enforcing the metal catalyst toward the remote C─H bonds needs well-judged catalyst design through proper ligand development. This review article aims to summarize the recent discoveries for the remote C─H borylation by the employment of new catalyst/ligand design with the help of steric of the ligand, noncovalent interactions. It has been found that C─H borylation now takes part in the total synthesis of natural products in a shorter route. Whereas, Ir-catalyzed C─H borylation is predominant, cobalt catalyst has also started to affect this field for sustainable and cost-effective development.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.