ArticleACS nano2023
Crystal Polymorph Selection Mechanism of Hard Spheres Hidden in the Fluid.
Article in ACS nano, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
4 citing papers in PubMed, 18 citations in OpenAlex.
- Building with Light: Photoactive Colloids as the Next Generation Meta-Atoms.Nano letters · 2026Review
- Capturing Structure and Morphology in Responsive Microgels: From Intrinsic Free Energy to Collective Behavior.Macromolecules · 2025Article
- Molecular Simulation of the Isotropic-to-Nematic Transition of Rod-like Polymers in Bulk and Under Confinement.Polymers · 2025Article
- Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
5 authors at 2 institutions in 3 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Nucleation plays a critical role in the birth of crystals and is associated with a vast array of phenomena, such as protein crystallization and ice formation in clouds. Despite numerous experimental and theoretical studies, many aspects of the nucleation process, such as the polymorph selection mechanism in the early stages, are far from being understood. Here, we show that the hitherto unexplained excess of particles in a face-centered-cubic (fcc)-like environment, as compared to those in a hexagonal-close-packed (hcp)-like environment, in a crystal nucleus of hard spheres can be explained by the higher order structure in the fluid phase. We show using both simulations and experiments that in the metastable fluid phase, pentagonal bipyramids, clusters with fivefold symmetry known to be inhibitors of crystal nucleation, transform into a different cluster, Siamese dodecahedra. These clusters are closely similar to an fcc subunit, which explains the higher propensity to grow fcc than hcp in hard spheres. We show that our crystallization and polymorph selection mechanism is generic for crystal nucleation from a dense, strongly correlated fluid phase.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.