ArticleLangmuir : the ACS journal of surfaces and colloids2023
Understanding Sorption Mechanisms Directly from Isotherms.
Article in Langmuir : the ACS journal of surfaces and colloids, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Adsorption of Forever Chemical Pollutants: The Physical Chemistry of PFAS Near Surfaces.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- A General-Purpose Model Adsorption Isotherm and Whole Isotherm Surface Area Measurement Method.ACS omega · 2026Article
- Surface Tension Isotherms: Reconceptualizing Adsorption, Self-Assembly, and Micelle Formation via the Fluctuation Theory.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Biosorption of synthetic dyes by live and dried marine diatomFrontiers in microbiology · 2026Article
- Optimizing sustainable pore design in MIL-125(Ti) for biomedicine using morphological tuning informed by Gaussian, Lorentzian, and Boltzmann fitting functions.Communications chemistry · 2025Article
- Accelerated Porosity Screening Using a Multichannel Colorimetric Array.Angewandte Chemie (International ed. in English) · 2025Article
- Optically Triggered Nucleation Eliminates Hydration Hysteresis in Swelling Minerals.Langmuir : the ACS journal of surfaces and colloids · 2025Article
- Integration of high strength, flexibility, and room-temperature plasticity in ceramic nanofibers.Nature communications · 2025Article
- Gas and Liquid Isotherms: The Need for a Common Foundation.Langmuir : the ACS journal of surfaces and colloids · 2025Review
- Surface chemistry and catalytic activity in HRSC advances · 2024Article
- Synergistic Solvation as the Enhancement of Local Mixing.The journal of physical chemistry. B · 2024Article
- Sorption Hysteresis: A Statistical Thermodynamic Fluctuation Theory.Langmuir : the ACS journal of surfaces and colloids · 2024Article
- Replacing the Langmuir Isotherm with the Statistical Thermodynamic Fluctuation Theory.The journal of physical chemistry letters · 2024Review
- Actual Amount Adsorbed as Estimated from the Surface Excess Isotherm.Langmuir : the ACS journal of surfaces and colloids · 2024Article
- Cooperativity in Sorption Isotherms.Langmuir : the ACS journal of surfaces and colloids · 2023Article
- Sorption from Solution: A Statistical Thermodynamic Fluctuation Theory.Langmuir : the ACS journal of surfaces and colloids · 2023Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Currently, more than 100 isotherm models coexist for the six IUPAC isotherm types. However, no mechanistic insights can be reached when several models, each claiming a different mechanism, fit an experimental isotherm equally well. More frequently, popular isotherm models [such as the site-specific models like Langmuir, Brunauer-Emmett-Teller (BET), and Guggenheim-Anderson-de Boer (GAB)] have been applied to real and complex systems that break their basic assumptions. To overcome such conundrums, we establish a universal approach to model all isotherm types, attributing the difference to the sorbate-sorbate and sorbate-surface interactions in a systematic manner. We have generalized the language of the traditional sorption models (such as the monolayer capacity and the BET constant) to the model-free concepts of partitioning and association coefficients that can be applied across the isotherm types. Through such a generalization, the apparent contradictions, caused by applying the site-specific models alongside with cross-sectional area of sorbates for the purpose of surface area determination, can be eliminated straightforwardly.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.