Evidence map›Paper›PMID 37065068›Full record

ArticleACS omega2023

Recyclable TPA-Modified MIL-88-Supported Ionic Pt as a Highly Efficient Catalyst for Alkene Hydrosilylation.

Muhua Chen, Peng Chen, Zhen Ji, Min Yu, Jihuai Tan, Bo Fu, Xinbao Zhu

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ACS omega, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.7field-weighted citation impact, top 34% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 5 citations in OpenAlex.

  1. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 1 institution in 1 country.

Muhua ChenJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.ORCID https://orcid.org/0000-0002-8383-5358
Peng ChenJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.
Zhen JiJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.
Min YuJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.
Jihuai TanJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.
Bo FuJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.ORCID https://orcid.org/0000-0002-0310-2075
Xinbao ZhuJiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, Jiangsu Provincial Key Lab for the Chemistry and Utilization of Agro-forest Biomass, College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China.ORCID https://orcid.org/0000-0001-7707-7362
Nanjing Forestry University · CN

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The hydrosilylation reaction driven by a homogeneous catalyst has been widely used in the industrial synthesis of functionalized silicone compounds. However, the homogeneous catalyst for hydrosilylation has the shortcomings of nonrecyclability, undesirable side reactions, and high cost. In this work, a highly efficient heterogeneous catalyst was prepared by loading Pt ions on MIL-88 modified with trimethoxy[3-(phenylamino)propyl]silane. In comparison with previous research studies, the resulting catalyst can exhibit high catalytic activity and excellent stability during the hydrosilylation reaction, which was attributed to the presence of a pyrrolic nitrogen structure between TPA-MIL-88 and the Pt ion. Besides them, 1.2%Pt/TPA-MIL-88 showed the highest catalytic activity and can be reused five times without significant deactivation. Importantly, 1.2%Pt/TPA-MIL-88 also achieved satisfactory results when it was used to catalyze the hydrosilylation reaction for other olefins, implying great potential for application in the silicone industry.

Identifiers

PMID37065068
PMCPMC10099423
OpenAlexW4362580858

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.