ArticleChemistry (Weinheim an der Bergstrasse, Germany)2023
Reactivity of a Strictly T-Shaped Phosphine Ligated by an Acridane Derived NNN Pincer Ligand.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed, 26 citations in OpenAlex.
- Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Phosphorescence of Heavy, T-Shaped Pnictogen Trisamides in Solution at Room Temperature in the Near-Infrared II Region.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Ambiphilic Reactivity and Switchable Methyl Transfer at a T-Shaped Bi(NNN) Complex Enabled by a Redox-Active Pincer Ligand.Journal of the American Chemical Society · 2026Article
- Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides.Chemical science · 2026Article
- Direct OJACS Au · 2025Article
- Phosphorus-Nitrogen Heterocycles Derived from Chelating N-Donor Ligands: Historical Advances, Recent Highlights, and Outlook.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Article
- Hydrogen splitting at a single phosphorus centre and its use for hydrogenation.Nature chemistry · 2024Article
- Combining geometric constraint and redox non-innocence within an ambiphilic PBiP pincer ligand.Chemical science · 2024Article
- Highly selective, reversible water activation by P,N-cooperativity in pyridyl-functionalized phosphinines.Chemical science · 2024Article
- Metallomimetic C-F Activation Catalysis by Simple Phosphines.Journal of the American Chemical Society · 2024Article
- Reactivity of a Strictly T-Shaped Phosphine Ligated by an Acridane Derived NNN Pincer Ligand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
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Authors and funding
3 authors at 3 institutions in 3 countries.
Funding
Abstract
The steric tuning of a tridentate acridane-derived NNN pincer ligand allows for the isolation of a strictly T-shaped phosphine that exhibits ambiphilic reactivity. Well-defined phosphorus-centered reactivity towards nucleophiles and electrophiles is reported, contrasting with prior reports on this class of compounds. Reactions towards oxidants are also described. The latter result in the two-electron oxidation of the phosphorus atom from +III to +V and are accompanied by a strong geometric distortion of the NNN pincer ligand. By contrast, cooperative activation of E-H (HCl, HBcat, HOMe) bonds proceeds with retention of the phosphorus redox state. When using H
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