Evidence map›Paper›PMID 37042122›Full record

ArticleThe Analyst2023

On the mechanism of the bipolar reference electrode.

Nicole L Walker, Jeffrey E Dick

Abstract read
In one paragraph

Article in The Analyst, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Measuring the Capacitance of Carbon in Ionic Liquids: From Graphite to Graphene.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

Nicole L WalkerDepartment of Chemistry, Purdue University, West Lafayette, IN 47907, USA. jdick@purdue.edu.ORCID http://orcid.org/0000-0002-9970-116X
Jeffrey E DickDepartment of Chemistry, Purdue University, West Lafayette, IN 47907, USA. jdick@purdue.edu.ORCID http://orcid.org/0000-0002-4538-9705

Funding

Nanoelectrochemistry and Single Cell MetabolomicsR35GM138133 · NIGMS · UNIV OF NORTH CAROLINA CHAPEL HILL · PI Jeffrey E Dick · 2020 to 2026
$2.7M
NIGMS NIH HHS R35 GM138133
6 · The paper itself

Abstract

Commercial silver/silver chloride (Ag/AgCl) reference electrodes are some of the most commonly used reference electrodes, but they suffer from a number of issues due to their porous frits. Such issues include difficulty miniaturizing, silver and chloride ion leakage, charge screening effects at low ionic strength, frit drying if left unattended in air, and incompatibility with organic solvents. To solve these issues, we recently designed a reference electrode that is leakless in principle by replacing the porous frit with a sealed, conductive wire, where the ends of the wire are exposed to the reference electrode solution and the working electrode solution. We hypothesized that the reference electrode operated like a closed, bipolar electrochemical cell, and we termed the name bipolar reference electrode (BPRE). Here, we provide evidence that the BPRE can either act as a reference electrode by operating through an ion transfer mechanism

Identifiers

PMID37042122
PMCPMC10308696

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.