Evidence map›Paper›PMID 37034542›Full record

ArticleNature water2023

Sulfate reduction accelerates groundwater arsenic contamination even in aquifers with abundant iron oxides.

Athena A Nghiem, Henning Prommer, M Rajib H Mozumder, Adam Siade, James Jamieson, Kazi Matin Ahmed, Alexander van Geen, Benjamin C Bostick

Abstract read
In one paragraph

Article in Nature water, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Athena A NghiemDepartment of Earth and Environmental Sciences, Columbia University, New York, NY, USA.ORCID 0000-0001-9135-0804
Henning PrommerCSIRO Environment, Wembley, Western Australia, Australia.ORCID 0000-0002-8669-8184
M Rajib H MozumderDepartment of Earth and Environmental Sciences, Columbia University, New York, NY, USA.ORCID 0000-0002-2243-1245
Adam SiadeCSIRO Environment, Wembley, Western Australia, Australia.ORCID 0000-0003-3840-5874
James JamiesonCSIRO Environment, Wembley, Western Australia, Australia.ORCID 0000-0002-6161-5020
Kazi Matin AhmedDepartment of Geology, University of Dhaka, Dhaka, Bangladesh.
Alexander van GeenLamont-Doherty Earth Observatory, Columbia University, Palisades, NY, USA.
Benjamin C BostickLamont-Doherty Earth Observatory, Columbia University, Palisades, NY, USA.ORCID 0000-0002-7513-6469

Funding

Training CoreP42ES010349 · NIEHS · COLUMBIA UNIVERSITY HEALTH SCIENCES · PI NAVAS-ACIEN, ANA · 2000 to 2020
$53.6M
True Metal fac coreP30ES009089 · NIEHS · COLUMBIA UNIVERSITY HEALTH SCIENCES · PI MATTHEW S PERZANOWSKI · 1998 to 2026
$44.7M
Research Experience and Training Coordination CoreP42ES033719 · NIEHS · COLUMBIA UNIVERSITY HEALTH SCIENCES · PI Ana Navas-Acien · 2022 to 2026
$11.9M
NIEHS NIH HHS P30 ES009089NIEHS NIH HHS P42 ES010349NIEHS NIH HHS P42 ES033719
6 · The paper itself

Abstract

Groundwater contamination by geogenic arsenic is a global problem affecting nearly 200 million people. In South and Southeast Asia, a cost-effective mitigation strategy is to use oxidized low-arsenic aquifers rather than reduced high-arsenic aquifers. Aquifers with abundant oxidized iron minerals are presumably safeguarded against immediate arsenic contamination, due to strong sorption of arsenic onto iron minerals. However, preferential pumping of low-arsenic aquifers can destabilize the boundaries between these aquifers, pulling high-arsenic water into low-arsenic aquifers. We investigate this scenario in a hybrid field-column experiment in Bangladesh where naturally high-arsenic groundwater is pumped through sediment cores from a low-arsenic aquifer, and detailed aqueous and solid-phase measurements are used to constrain reactive transport modelling. Here we show that elevated groundwater arsenic concentrations are induced by sulfate reduction and the predicted formation of highly mobile, poorly sorbing thioarsenic species. This process suggests that contamination of currently pristine aquifers with arsenic can occur up to over 1.5 times faster than previously thought, leading to a deterioration of urgently needed water resources.

Identifiers

PMID37034542
PMCPMC10074394

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.