ArticleProceedings of the National Academy of Sciences of the United States of America2023
Colloidal superionic conductors.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed, 5 citations in OpenAlex.
- Probing anharmonic and heterogeneous carrier dynamics across sublattice melting in a minimal model superionic conductor.Proceedings of the National Academy of Sciences of the United States of America · 2026Article
- Ion-Size Controlled Non-Classical Crystallization of Metal-Oxide Nanoparticles Covered with a Few Highly Charged Ligands.Journal of the American Chemical Society · 2026Article
- Morphology-Transport Coupling and Dissipative Structures in PEO-PS+LiTFSI Electrolytes In-Operando Conditions.ACS applied materials & interfaces · 2025Article
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
Nanoparticles with highly asymmetric sizes and charges that self-assemble into crystals via electrostatics may exhibit behaviors reminiscent of those of metals or superionic materials. Here, we use coarse-grained molecular simulations with underdamped Langevin dynamics to explore how a binary charged colloidal crystal reacts to an external electric field. As the field strength increases, we find transitions from insulator (ionic state), to superionic (conductive state), to laning, to complete melting (liquid state). In the superionic state, the resistivity decreases with increasing temperature, which is contrary to metals, yet the increment decreases as the electric field becomes stronger. Additionally, we verify that the dissipation of the system and the fluctuation of charge currents obey recently developed thermodynamic uncertainty relation. Our results describe charge transport mechanisms in colloidal superionic conductors.
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Registered trials
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