Evidence map›Paper›PMID 37014945›Full record

ArticleJournal of the American Chemical Society2023

Interrogating the Mechanistic Features of Ni(I)-Mediated Aryl Iodide Oxidative Addition Using Electroanalytical and Statistical Modeling Techniques.

Tianhua Tang, Avijit Hazra, Daniel S Min, Wendy L Williams, Eli Jones, Abigail G Doyle, Matthew S Sigman

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 36 papers.

0numbers the graph read from it
0cells of the map it votes in
36citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

36 citing papers in PubMed.

  1. Article
  2. Review
  3. Nickel-Catalyzed Cross-Dehydrogenative Allylation of Aldehydes.Journal of the American Chemical Society · 2026
    Article
  4. General and selective nickel-electrocatalyzed cross-electrophile C*(Proceedings of the National Academy of Sciences of the United States of America · 2026
    Article
  5. Advances in NiACS catalysis · 2026
    Review
  6. Article
  7. Article
  8. Article
  9. Discovery of NiJournal of the American Chemical Society · 2025
    Article
  10. Article
  11. Article
  12. Article
  13. Evidence for a Unifying NiJournal of the American Chemical Society · 2025
    Article
  14. Red-Light-ActiveJournal of the American Chemical Society · 2025
    Article
  15. Article
  16. Article
  17. Article
  18. Selective Ni(I)/Ni(III) Process for Consecutive Geminal C(spJournal of the American Chemical Society · 2024
    Article
  19. Article
  20. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Tianhua TangDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United States.
Avijit HazraDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United States.ORCID 0000-0002-1102-8581
Daniel S MinDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States.
Wendy L WilliamsDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States.ORCID 0000-0003-2227-0856
Eli JonesDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United States.ORCID 0000-0003-4381-7427
Abigail G DoyleDepartment of Chemistry and Biochemistry, University of California, Los Angeles, California 90095, United States.ORCID 0000-0002-6641-0833
Matthew S SigmanDepartment of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, United States.ORCID 0000-0002-5746-8830

Funding

Pd-Catalyzed Olefin Functionalization Reactions for Organic SynthesisR01GM063540 · NIGMS · UNIVERSITY OF UTAH · PI SIGMAN, MATTHEW S · 2002 to 2019
$5.3M
EXTRAMURAL RESEARCH FACILITIES CONSTRUCTIONC06RR017539 · NCRR · UNIVERSITY OF UTAH · PI PUGMIRE, RONALD J · 2003 to 2003
$3.8M
New Directions in Nickel and Photoredox CatalysisR35GM126986 · NIGMS · UNIVERSITY OF CALIFORNIA LOS ANGELES · PI Abigail Gutmann Doyle · 2018 to 2026
$3.7M
A 500MHz NMR Spectrometer with AutomationS10OD025241 · OD · UNIVERSITY OF UTAH · PI FLYNN, PETER F · 2018 to 2018
$600k
NCRR NIH HHS C06 RR017539NIGMS NIH HHS R01 GM063540NIGMS NIH HHS R35 GM126986NIH HHS S10 OD025241
6 · The paper itself

Abstract

While the oxidative addition of Ni(I) to aryl iodides has been commonly proposed in catalytic methods, an in-depth mechanistic understanding of this fundamental process is still lacking. Herein, we describe a detailed mechanistic study of the oxidative addition process using electroanalytical and statistical modeling techniques. Electroanalytical techniques allowed rapid measurement of the oxidative addition rates for a diverse set of aryl iodide substrates and four classes of catalytically relevant complexes (Ni(

Identifiers

PMID37014945
PMCPMC10548350

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.