ReviewBeilstein journal of organic chemistry2023
Group 13 exchange and transborylation in catalysis.
Review in Beilstein journal of organic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
2 citing papers in PubMed.
- Zintl Clusters as a Platform for Lewis Acid Catalysis.Inorganic chemistry · 2024Article
- Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene.Chemical science · 2024Article
Corrections and comments
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Authors and funding
2 authors.
Funding
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Abstract
Catalysis is dominated by the use of rare and potentially toxic transition metals. The main group offers a potentially sustainable alternative for catalysis, due to the generally higher abundance and lower toxicity of these elements. Group 13 elements have a rich catalogue of stoichiometric addition reactions to unsaturated bonds but cannot undergo the redox chemistry which underpins transition-metal catalysis. Group 13 exchange reactions transfer one or more groups from one group 13 element to another, through σ-bond metathesis; where boron is both of the group 13 elements, this is termed transborylation. These redox-neutral processes are increasingly being used to render traditionally stoichiometric group 13-mediated processes catalytic and develop new catalytic processes, examples of which are the focus of this review.
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Registered trials
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