Near-IR Absorbers Based on Pt(II)-Dithiolene Donor-Acceptor Charge-Transfer (CT) Systems: A Structural Analysis to Highlight DA Interactions.

Davide Espa, Luca Pilia, Flavia Artizzu, Angela Serpe, Paola Deplano, Luciano Marchiò

Abstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Davide EspaDipartimento di Scienze Chimiche e Geologiche, Università di Cagliari, Unità di Ricerca dell'INSTM, S.S. 554-Bivio per Sestu, 09042 Cagliari, Italy.

Luca PiliaDipartimento di Ingegneria Meccanica Chimica e dei Materiali, Università di Cagliari, Via Marengo 2, 09123 Cagliari, Italy.ORCID 0000-0001-8753-7094

Flavia ArtizzuDipartimento per lo Sviluppo Sostenibile e la Transizione Ecologica (DiSSTE), Università del Piemonte Orientale "A. Avogadro", Piazza S. Eusebio 5, 13100 Vercelli, Italy.ORCID 0000-0003-3773-2806

Angela SerpeDipartimento di Ingegneria Civile, Ambientale e Architettura, INSTM Research Unit, Università di Cagliari, Via Marengo 2, 09123 Cagliari, Italy.ORCID 0000-0002-3476-0636

Paola DeplanoDipartimento di Scienze Chimiche e Geologiche, Università di Cagliari, Unità di Ricerca dell'INSTM, S.S. 554-Bivio per Sestu, 09042 Cagliari, Italy.

Luciano MarchiòDipartimento di Scienze Chimiche della Vita e della Sostenibilità Ambientale, Università di Parma, Parco Area delle Scienze 17/a, 43124 Parma, Italy.ORCID 0000-0002-0025-1104

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The packing interactions of a series of electron donor (D) and electron acceptor (A) charge transfer (CT) near-IR absorbers based on platinum-dithiolene complexes are reinvestigated here as a case study also by using the Hirshfeld surface analysis. This analysis on systems, which exhibit the 1:1, 2:1 and 2:2 columnar stacking patterns between D and A, allows us to point out that several interactions of atoms and fragments are involved in the stacking interactions but also that only a limited fraction of these interactions, limited to the 1:1 D/A columnar stacking case, can be relatable to the absorption features of this class of compounds.

Indexed as

charge transferdonor–acceptorHirshfeld analysisnear-IR absorbersPt-dithiolenesstacking

Identifiers

PMID36985538

DOI10.3390/molecules28062566

PMCPMC10052144

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.