ArticleMaterials (Basel, Switzerland)2023
CALPHAD-Based Modelling of the Temperature-Composition-Structure Relationship during Physical Vapor Deposition of Mg-Ca Thin Films.
Article in Materials (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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2 citing papers in PubMed.
- Preparation and Characterization of Oxide Coatings with LDH Nanosheets on AZ91 Magnesium Alloy by a One-Step Low Voltage Microarc Oxidation Process.Materials (Basel, Switzerland) · 2026Article
- Insights into the Corrosion Behavior of Pure Magnesium and Magnesium-Calcium Alloy (Mg-1.8 at.% Ca) in Thin-Film and Bulk Forms.Materials (Basel, Switzerland) · 2025Article
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Abstract
The temperature-dependent composition and phase formation during the physical vapor deposition (PVD) of Mg-Ca thin films is modeled using a CALPHAD-based approach. Considering the Mg and Ca sublimation fluxes calculated based on the vapor pressure obtained by employing thermochemical equilibrium calculations, the experimentally observed synthesis-temperature trends in the thin-film composition and phase formation were reproduced. The model is a significant step towards understanding how synthesis parameters control composition and, therefore, phase formation in the PVD of metals with high vapor pressures.
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