ArticleJournal of the American Chemical Society2023
Anion Intercalation into Graphite Drives Surface Wetting.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Operando Optical Imaging Reveals Beyond-Meniscus Nanoelectrochemistry Mediated by a Nanometric Wetting Film.Chemical & biomedical imaging · 2026Article
- Voltammetry Prediction and Electrochemical Analysis of Carbon Material from "Salt-In-Water" to "Water-In-Salt".Analytical chemistry · 2025Article
- Unlocking Mesoscopic Disorder in Graphitic Carbon with Spectroelectrochemistry.Angewandte Chemie (International ed. in English) · 2025Article
- Unraveling the Stability of Layered Intercalation Compounds through First-Principles Calculations: Establishing a Linear Free Energy Relationship with Aqueous Ions.ACS physical chemistry Au · 2024Article
- Measuring the Capacitance of Carbon in Ionic Liquids: From Graphite to Graphene.The journal of physical chemistry. C, Nanomaterials and interfaces · 2024Article
- Relation between Double Layer Structure, Capacitance, and Surface Tension in Electrowetting of Graphene and Aqueous Electrolytes.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The unique layered structure of graphite with its tunable interlayer distance establishes almost ideal conditions for the accommodation of ions into its structure. The smooth and chemically inert nature of the graphite surface also means that it is an ideal substrate for electrowetting. Here, we combine these two unique properties of this material by demonstrating the significant effect of anion intercalation on the electrowetting response of graphitic surfaces in contact with concentrated aqueous and organic electrolytes as well as ionic liquids. The structural changes during intercalation/deintercalation were probed using in situ Raman spectroscopy, and the results were used to provide insights into the influence of intercalation staging on the rate and reversibility of electrowetting. We show, by tuning the size of the intercalant and the stage of intercalation, that a fully reversible electrowetting response can be attained. The approach is extended to the development of biphasic (oil/water) systems that exhibit a fully reproducible electrowetting response with a near-zero voltage threshold and unprecedented contact angle variations of more than 120° within a potential window of less than 2 V.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.