ArticleACS nano2023
Black Phosphorus Degradation during Intercalation and Alloying in Batteries.
Article in ACS nano, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
6 citing papers in PubMed.
- Saturating the Matrix: Nanocomposite Solution-Processed Sodium Aluminophosphate Solid Electrolytes.ACS applied energy materials · 2025Article
- Structural Evolution of Silicon Nitride Anodes during Electrochemical Lithiation.ACS electrochemistry · 2025Article
- Recent advances in characterization of rechargeable battery materialsJournal of materials chemistry. A · 2025Article
- A DFT Study of Band-Gap Tuning in 2D Black Phosphorus via LiInternational journal of molecular sciences · 2024Article
- Electrochemical Atomic Force Microscopy of Black Phosphorus Composite Anodes: Electrode Destabilization and Degradation Mechanisms in Alkali-Ion Batteries.ACS applied materials & interfaces · 2024Article
- Synthesis of Black Phosphorene Quantum Dots from Red Phosphorus.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Numerous layered materials are being recognized as promising candidates for high-performance alkali-ion battery anodes, but black phosphorus (BP) has received particular attention. This is due to its high specific capacity, due to a mixed alkali-ion storage mechanism (intercalation-alloying), and fast alkali-ion transport within its layers. Unfortunately, BP based batteries are also commonly associated with serious irreversible losses and poor cycling stability. This is known to be linked to alloying, but there is little experimental evidence of the morphological, mechanical, or chemical changes that BP undergoes in operational cells and thus little understanding of the factors that must be mitigated to optimize performance. Here the degradation mechanisms of BP alkali-ion battery anodes are revealed through
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